Semnan University Press Applied Chemistry Today 2981-2437 19 71 2024 06 21 Synthesis, characterization and X-ray crystal structure of a new cocrystal complex of and preparation the related nano cadmium (II) oxide Synthesis, characterization and X-ray crystal structure of a new cocrystal complex of and preparation the related nano cadmium (II) oxide 9 22 8228 10.22075/chem.2023.30794.2183 FA Younes Hanifehpour Department of Chemistry, Sayyed Jamaleddin Asadabadi University, Asadabad 6541853096, Iran Babak Mirtamizdoust Department of Chemistry, Faculty of Science, Qom University, Qom, Iran Reza Golbedaghi Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran Journal Article 2023 07 05 In this work, A novel novel cadmium (II) co-crystal binary coordination compound with 3- FBINH ligand and nitrate anionic ligand were synthesized and characterized. The structure of co-crystal (3- FBINH is the abbreviation of 3- flouro benzylidene iso nicotine hydrazide) ([Cd (3-FBINH)2 (NO3)2 (H2O)] [Cd (3-FBINH)2 (NO3) (C2H6O) (H2O)].NO3 (1) was characterized by single-crystal X-ray analysis. The X-ray structure revealed that the compound has two Cd (II) metal centers with 7 and 6 coordination numbers. The adjacent frameworks connected by labile interactions like strong hydrogen -bonding interactions, CH …π interactions CH …CH interactions that the self-assembly occurs in the structure. <br />Consequently, the labile interactions also allow the structure to form a 3D supramolecular coordination system. Cd O nanoparticles were obtained by thermolysis of 1 at 550 °C. The morphology and size of the prepared Cd O nanoparticles were further studied using SEM and In this work, A novel novel cadmium (II) co-crystal binary coordination compound with 3- FBINH ligand and nitrate anionic ligand were synthesized and characterized. The structure of co-crystal (3- FBINH is the abbreviation of 3- flouro benzylidene iso nicotine hydrazide) ([Cd (3-FBINH)2 (NO3)2 (H2O)] [Cd (3-FBINH)2 (NO3) (C2H6O) (H2O)].NO3 (1) was characterized by single-crystal X-ray analysis. The X-ray structure revealed that the compound has two Cd (II) metal centers with 7 and 6 coordination numbers. The adjacent frameworks connected by labile interactions like strong hydrogen -bonding interactions, CH …π interactions CH …CH interactions that the self-assembly occurs in the structure. <br />Consequently, the labile interactions also allow the structure to form a 3D supramolecular coordination system. Cd O nanoparticles were obtained by thermolysis of 1 at 550 °C. The morphology and size of the prepared Cd O nanoparticles were further studied using SEM and https://chemistry.semnan.ac.ir/article_8228_58d4af8dd43f23e7ce29fcbd623aa58d.pdf