A very sensitive, simple and selective spectrophotometric method for simultaneous determination of phosphate and silicate based on formation of phospho- and silicomolybdenum blue complexes in the presence of ascorbic acid is described. Although the complexes of phosphate and silicate with reagent show a spectral overlap, they have been simultaneously determined by partial least squares (PLS). The linear range was 0.01-2.80 μg ml-1 for phosphate and 0.02-3.00 μg ml-1 for silicate. Interference effects of common anions and cations were studied and the proposed method was also applied satisfactorily to the determination of phosphate and silicate in synthetic detergents.
Nekoei,M , Mohammadhossein,M and Bagheri,H . (2009). Simultaneous spectrophotometric determination of phosphate and silicate by using partial least squares method. Applied Chemistry Today, 4(10), 45-57. doi: 10.22075/chem.2017.548
MLA
Nekoei,M , , Mohammadhossein,M , and Bagheri,H . "Simultaneous spectrophotometric determination of phosphate and silicate by using partial least squares method", Applied Chemistry Today, 4, 10, 2009, 45-57. doi: 10.22075/chem.2017.548
HARVARD
Nekoei M, Mohammadhossein M, Bagheri H. (2009). 'Simultaneous spectrophotometric determination of phosphate and silicate by using partial least squares method', Applied Chemistry Today, 4(10), pp. 45-57. doi: 10.22075/chem.2017.548
CHICAGO
M Nekoei, M Mohammadhossein and H Bagheri, "Simultaneous spectrophotometric determination of phosphate and silicate by using partial least squares method," Applied Chemistry Today, 4 10 (2009): 45-57, doi: 10.22075/chem.2017.548
VANCOUVER
Nekoei M, Mohammadhossein M, Bagheri H. Simultaneous spectrophotometric determination of phosphate and silicate by using partial least squares method. Applied Chemistry Today. 2009;4(10):45-57 (In Persian). doi: 10.22075/chem.2017.548
