Simultaneous removal of Cd(II), Ni(II), and Cr(III) ions from industrial wastewater by chitosan- dendrimer composite using ICP-OES

Document Type : Original Article

Abstract

Generation 2 polyamidoamine (PAMAM) dendrimer with ethylenediamine cores (G2.O) were grafted on chitosan (CS) and evaluate as new absorbent materials. Fourier transform infrared (FT-IR) spectra data characterized that the effective graft of PAMAM onto CS and synthesis of chitosan-dendrimer (CS-PAMAM) as new adsorbent. Effect of new adsorbent onto removal of cadmium, chromium and nickel ions which are classical pollutions commonly found in industrial wastewater are investigated. Effective factors that influenced the removal efficiency of metal ions are: pH of solution, contact time, initial concentration of cations ions and dose of adsorbent were studied by inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. Metal ion removal was achieved over a large-scale metal concentration within 30 minutes equilibrium time and Maximum removal of cations of heavy metal ion was obtained at  for both Cd(II) and Cr(III), and  for Ni(II). Kinetic studies showed that adsorption process of Cr(III), Cd(II) and Ni(II) followed the pseudo-second-order kinetic model. Equilibrium adsorption isotherm data indicated a good fit to the Langmuir isotherm and the maximum adsorption capacities for the Cr(III), Cd(II) and Ni(II) were 47.074, 25.814 and  ,respectively. Overall, results of the study demonstrate the potential of CS-PAMAM as new adsorbent for the removal of heavy metals from aqueous solutions.    

Keywords

References

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Applied Chemistry Today
Volume 12, Issue 43
June 2017
Pages 151-170

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