Photodegradation of Eriochrome Black T Using TMU-16 Metal-Organic Framework

Document Type : Original Article

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Abstract

Development of wastewater treatment methods has become a hot research topic. The advanced oxidation processes (AOPs) have attracted much attention as a method for degrading a wide range of non-biodegradable and harmful organic pollutants into less toxic compounds. In this work, TMU-16 a two-fold interpenetrated mesoporous MOF as a heterogeneous catalyst was employed to photodegradation of Eriochrome Black T under UV irradiation from aqueous solution. Some parameters such as pH, catalyst amount and dye concentration which affect the efficiency of the degradation were studied. From kinetic studies, the degradation producer is the pseudo-first-order. The detection of hydroxyl radicals with probe molecule and perform degradation in the absence of O2 molecules revealed that degradation occurred by mediated these radicals. The results shown, that TMU-16 should be effective photocatalyst for dyes degradation.

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References

[1] G. Crini, Bioresour. Technol. 97 (2006) 1061.
[2] A. Mittal, A. Malviya, D. Kaur, J. Mittal and L. Kurup, J. Hazard. Mater. 148 (2007) 229.
[3] S. Chen, J. Zhang, C. Zhang, Q. Yue, Y. Li and C. Li, Desalination, 252 (2010) 149.
[4] Q. Qin, J. Ma and K. Liu, J. Hazard. Mater. 162 (2009) 133.
[5] U. I. Gaya and A. H. Abdullah, J. Photochem. Photobiol. C, 9 (2008) 1.
[6] D. Wang, T. Silbaugh, R. Pfeffer and Y. Lin, Powder Technol. 203 (2010) 298.
[7] D. Lin, Q. Zhao, L. Hu and B. Xing, Chemosphere, 103 (2014) 188.
[8] M. N. Chong, B. Jin, C. W. Chow and C. Saint, Water Res. 44 (2010) 2997.
[9] D. H. Bremner, R. Molina, F. Martínez, J. A. Melero and Y. Segura, Appl. Catal. B, 90 (2009) 380.
[10] M. I. Litter, Appl. Catal. B, 23 (1999) 89.
[11] K. Nakata and A. Fujishima, J. Photochem. Photobiol. C, 13 (2012) 169.
[12] A. Janczyk, E. Krakowska, G. Stochel and W. Macyk, J. Am. Chem. Soc. 128 (2006) 15574.
[13] A. Hajesmaili and Z. Bahrami, JAC, 11 (2017) 91.
[14] U. Akpan and B. Hameed, J. Hazard. Mater. 170(2009) 520.
[15] K. Ayoub, E. D. van Hullebusch, M. Cassir and A. Bermond, J. Hazard. Mater. 178 (2010) 10.
[16] A. Mills and S. Le Hunte, J. Photochem. Photobiol. A, 108 (1997) 1.
[17] J. Lü, J.-X. Lin, X.-L. Zhao and R. Cao, Chem. Commun. 48 (2012) 669.
[18] H. Yang and H. Cheng, Sep. Purif. Technol. 56 (2007) 392.
[19] O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi and J. Kim, Nature, 423 (2003) 705.
[20] M. Alvaro, E. Carbonell, B. Ferrer, F. X. Llabrés i Xamena and H. Garcia, Chem.-Eur. J. 13 (2007) 5106.
[21] M. C. Das, H. Xu, Z. Wang, G. Srinivas, W. Zhou, Y.-F. Yue, V. N. Nesterov, G. Qian and B. Chen, Chem. Commun. 47 (2011) 11715.
[22] K. G. M. Laurier, F. Vermoortele, R. P. Ameloot, D. De Vos, J. Hofkens and M. B. J. Roeffaers, J. Am. Chem. Soc. 135 (2013) 14488.
[23] J.-J. Dua, Y.-P. Yuan, J.-X. Sun, F.-M. Peng, X. Jiang, L.-G. Qiu, A.-J. Xie, Y.-H. Shen and J.-F. Zhu, J. Hazard. Mater. 190 (2011) 945.
[24] C.-C. Wang, J.-R. Li, X.-L. Lv, Y.-Q. Zhang and G. Guo, Energy Environ. Sci. 7 (2014) 2831.
[25] E. M. Dias and C. Petit, J. Mater. Chem. A, 3 (2015) 22484.
[26] R. Kaur, K. Vellingiri, K.-H. Kim, A. K. Paul and A. Deep, Chemosphere 154 (2016) 620.
[27] V. Safarifard and A. Morsali, CrystEngComm. 16 (2014) 8660.
[28] D. M. Ciurtin, Y.-B. Dong, M. D. Smith, T. Barclay and H.-C. Loye, Inorg. Chem. 40 (2001) 2825.
[29] M. Roushani, M. Mavaei and H. R. Rajabi, J. Mol. Catal. A: Chem. 409 (2015) 102.
[30] H. Kisch and S. Sakthive, Angew. Chem. Int. Ed. 42 (2003) 4908.
[31] N. Z. Logar and V. Kaučič, Acta Chim. Slov. 53 (2006) 117.
[32] W. Jiang, J. A. Joens, D. D. Dionysiou and K. E. O'Shea, J. Photochem. Photobiol. A, 262 (2013) 7.
[33] H. Al-Ekabi and N. Serpone, J. Phys. Chem. 92 (1988) 5726.
[34] S. Kalpagam and T. Kannadasan, JCBPSC, 4 (2014) 1936.
[35] A. Gautam, A. Kshirsagar, R. Biswas, S. Banerjee and P. K. Khann, RSC Adv. 6 (2016) 2746.
[36] S. K. Kansal, S. Sood, A. Umar and S.K. Mehta, Alloys Compd. 581 (2013) 392.
[37] I. Kazeminezhad and A. Sadollahkhani, Mater. Lett. 120 (2014) 267.
[38] P. Singla, M. Sharma, O. P. Pandey and K. Singh, Appl. phys. A, 116 (2014) 371.
Applied Chemistry Today
Volume 13, Issue 46
March 2018
Pages 29-44

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