Synthesis, characterization and theoretical calculations of some new Cu(II), Co(II), Ni(II) and Cd(II) Schiff base complexes incorporating piperazine head unit

Document Type : Original Article

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Abstract

Eight new [NiL1] (1), [CuL1] (2), [CoL1] (3) and [CdL1] (4), [NiL2] (5), [CuL2] (6), [CoL2] (7) and [CdL2] (8) complexes were prepared by the reaction of two new Schiff base ligands and Ni(II), Cu(II), Co(II) and Cd(II) metal ions in equemolar ratios. The ligands, H2L1 and H2L2, were synthesized by reaction of N,N'(2-aminoethyl)(3-aminopropyl)piperazine and 2-hydroxybenzaldehyde or 2-hydroxy-3-methoxy-benzaldehyde while characterized with IR  and 1H, 13C NMR spectroscopy. All complexes have been studied with IR and microanalysis. Theoretical calculations of relevant complexes are done by using one of the hybrid density functional theories which is B3LYP method with GEN keyword.

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References

[1] M. Rezaeivala and H. Keypour, Coord. Chem. Rev., 280 (2014) 203.
[2] N. F. Curtis, Coord. Chem. Rev., 3 (1968) 3.
[3] A. E. Martell, J. Perutka, and D. Kong, Coord. Chem. Rev., 216-217 (2001) 55.
[4] L. F. Lindoy, “The chemistry of macrocyclic ligand complexes” Cambridge University Press, (1989).
[5] R. Rella, A. Serra, A. Siciliano, A. Tapore, L.Valli and A. Zacco, Supramolecular Science, 4 (3-4) (1997) 461.
[6] K. Rissanen, J. Breitenbach and J. Huuskonen, J. Chem. Soc., Chem. Commun., (1994) 1265.
[7]  J. Huuskonen, J. Schulz  and K. Rissanen, Liebigs Annalen., (1995) 1515.
[8] S. Loukiala, J. Ratilainen, J. Valkonen and K. Rissanen, Acta Chem. Scand., 51 (1997) 1162.
 [9] K. Airola, J. Ratilainen, T. Nyrönen and K. Rissanen, Inorg. Chim. Acta, 277 (1998) 55.
[10] R. D. Hancock, A. Evers, M. P. Ngwenya, and P. W. Wade, J. Chem. Soc., Chem. Commun. (1987)1129.
[11] J. G. Gibson and E. D. McKenzie, J. Chem. Soc., Dalton Trans., (1974) 989.
[12] G. D. Fallon and M. S. Murray, B. Spethmann, J. K. Yandell, J. H.  Hodgkin and B. C.  Loft, J. Chem. Soc., Chem. Commun., (1984) 1561.
[13] F. Moise, W. T. Pennington, G. H. Robinson, and S. A. Sangokoya, Acta Crystallogr, C46 (1990) 1110.
 [14] H. Keypour, M. Rezaeivala, L. Valencia and P. Perez-Lourido, Polyhedron, 27 (2008) 3172.
[15] H. Keypour, M. Rezaeivala, L. Valencia, S. Salehzadeh, P. Perez-Lourido and H. Khavasi, Polyhedron 28 (2009) 3533.
[16] H. Keypour, M. Rezaeivala, L. Valencia, P. Perez-Lourido and A. H. Mahmoudkhani, Polyhedron 28 (2009) 3415-3418.
[17] H. Keypour, M. Rezaeivala, L. Valencia, P. Perez-Lourido and H. Khavasi, Polyhedron, 28 ( 2009) 3755.
[18] H. Keypour, N. Rahpeyma, P. Arzhangi, M. Rezaeivala, Y. Elerman, O. Buyukgungor and L. Valencia, Polyhedron 29 ( 2010) 1144.
[19] H. Keypour, P. Arzhangi, N. Rahpeyma, M. Rezaeivala, Y. Elerman, O. Buyukgungor, L. Valencia and  H.R. Khavasi, J. Mol. Struct., 977 (2010) 6.
[20] H. Keypour, P. Arzhangi, N. Rahpeyma, M. Rezaeivala, Y. Elerman and H. R. Khavasi, Inorg. Chim. Acta, 367 (2011) 9.
[21] H. Keypour, N. Rahpeyma, M. Rezaeivala, P. Arzhangi, M. Bayat, L. Valencia, Y. Elerman and O. Buyukgungor, Polyhedron  51 (2013) 117.
[22] GaussView, Version 5, Roy Dennington, Todd Keith, and John Millam, Semichem Inc., Shawnee Mission, KS, 2009.
[23] Gaussian 09, Revision C.01, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, Ö. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski, and D. J. Fox, Gaussian, Inc., Wallingford CT, 2009.
[24] PerkinElmer, ChemBioDraw Ultra Version (13.0.0.3015), CambridgeSoft Waltham, MA, USA, 2012.
[25] M. W. Wong, M. J. Rrish and K. B. Wieberg, J. Am. Chem. Soc., 113 (1991) 4776.
 [26] A. D. Becke, J.Chem.Phys., 98 (1993) 5648.
[27] C. Lee, W. Yang and R.G. Parr, Phys. Rev. B, 37 (1988) 785.
[28] V. A. Rassolov, M. A. Ratner, J. A. Pople, P. C. Redfern and  L. A. Curtiss, J. Comp. Chem., 22 (2001) 976.
[29] P. J. Hay and W. R. Wadt, J. Chem. Phys., 82 (1985) 299.
[30] W. R. Wadt and P. J. Hay, J. Chem. Phys., 82 (1985) 284.
 [31] N. S. Gill, R. H. Nutall and D. E. Scaife, J. Inorg. Nucl. Chem.18 (1961) 79.
[32] K. Sayın and D. Karakas, Corros. Sci., 77 (2013) 37.
[33] A. Najiya, C. Yohannan Panicker, M. Sapnakumari, B. Narayana, B. K. Sarojini and C. Van Alsenoy, Spectrochim. Acta A., 133 (2014) 526.
Applied Chemistry Today
Volume 13, Issue 46
March 2018
Pages 353-366

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