Synthesis, characterization and crystal structure of a new tetraaza macrocycle with m-xylyl spacer

Document Type : Original Article

Author

Applied Chemistry Department, Faculty of Science, Ardebil University of Mohaghegh, Ardebil

Abstract

The new [2+2] macrocyclic ligand with N4 donor set, from the [2+2] condensation of benzene-1,3-dicarboxaldehyde and 2,2- dimethylpropylenediamine  was synthesized by high dilution method and confirmed by IR, 1H NMR, 13C NMR, elemental analysis and crystal structure determination. Resonance data investigation of the compound indicates highly symmetrical structure for the macrocyclic ligand consists of two N2 donor sets. The compound is crystallized in the monoclinic system with space group C2/c. The metric parameters of the molecule show that a twofold axis bisects the macrocycle, passing through the cavity of the macrocycle.

Keywords

References

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]25[ حسینی صدر، موید، دانشگاه شهید مدنی آذربایجان، مجله شیمی کاربردی، شماره 38 (1395) ص 165.
Applied Chemistry Today
Volume 13, Issue 46
March 2018
Pages 327-342

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