Synthesis and Characterization of Immobilized Polyoxophosphomolybdate on the Surface of Magnetic Nanoparticles as Recoverable and Efficient New Catalyst for Epoxidation of Olefins

Document Type : Original Article

Authors

1 Assistant professor of inorganic chemistry, Department of Chemistry, Faculty of Sciences, University of Guilan, P.O. Box 41335-1914, Rasht / Iran

2 Department of Basic Sciences, Golpayegan University of Technology, P.O. Box 8771765651, Golpayegan, Iran

3 Department of Chemistry, Sharif University of Technology, Azadi Ave., P.O. Box 11155–3516, Tehran, Iran

4 Professor, Ph.D. in Inorganic Chemistry, Sharif University of Technology, Tehran , Iran

Abstract

New nanocatalyst Fe3O4@MnPOM, was successfully synthesized by covalent bonding of polyoxomolybdate [PMnMo11O39]5‒ on the amino-functionalized Fe3O4@SiO2. The synthesized nanomaterials were characterized by a series of spectroscopic techniques including X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray (EDX) and infrared spectroscopy (FT–IR). The resulting nanocomposites were efficient catalyst for selective oxidation of olefins to corresponding epoxides with t–BuOOH as oxidant, in high yields and selectivity. In addition, the synthesized catalyst could be conveniently recovered from reaction mixture using applying an external magnet. The recycling tests showed that the nanocatalyst can be reused at least 7 times without significant loss of catalytic efficiency.

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References

[1]Y. Zhu, Q. Wang, R.G. Cornwall, Y. Shi, Chemical Reviews, 114 (2014) 8199.
]2[ امینی، مجتبی، مجله شیمى کاربردى، شماره 38 (1395) ص 85.
[3] X. Zheng, L. Zhang, J. Li, S. Luo, J–P Cheng, Chemical Communications, 47 (2011) 12325.
[4] S.A. Jadhav, R. Bongiovanni, Advanced Materials Letters, 3 (2012) 356.
[5] R.Y. Hong, B. Feng, L.L. Chen, G.H. Liu, H.Z. Li,  Y. Zheng, D.G. Wei, Biochemical Engineering Journal, 42 (2008) 290.
[6] W. Xie, N.Ma, Energy & Fuels, 23 (2009) 1347.
[7] L. Chen, L. Wu, F. Liu, X.Qi, Y. Ge, S. Shen, Journal of Materials Chemistry B, 4 (2016) 3660.
[8] M.I. Majeed, Q. Lu, W. Yan, Z. Li, I. Hussain, M.N. Tahir, W. Tremel, B. Tan, Journal of Materials Chemistry B, 1 (2013) 2874.
]9[ بهمئی، منوچهر; عباسی، لاله; فرجی، محمد، مجله شیمى کاربردى، شماره 26 (1392) ص 29.
[10] Z. Moradi-Shoeili, M. Zare, M. Bagherzadeh, S. Özkar, S. Akbayrak, Journal of Coordination Chemistry, 69 (2016) 668.
[11] D. Dupont, J. Luyten, M. Bloemen, T. Verbiest, K. Binnemans, Industrial & Engineering Chemistry Research, 53 (2014) 15222.
[12] D. Wang, D. Astruc, Chemical Reviews, 114 (2014) 6949.
[13] S. Shylesh, J. Schweizer, S. Demeshko, V. Schunemann, S. Ernst, W.R. Thiel, Advanced Synthesis & Catalysis, 351 (2009) 1789.
[14] R.K. Sharma, S.Dutta, S. Sharma, Dalton Transactions, 44 (2015) 1303.
[15] Z. Moradi-Shoeili, M.  Zare, M. Bagherzadeh, Journal of Nanoparticle Research, 18 (2016) 298.
[16] M. Zare, Z. Moradi-Shoeili, M. Bagherzadeh, S. Akbayrak, S. Özkar, New Journal of Chemistry, 40 (2016) 1580.
[17] M. Zare, Z. Moradi‐Shoeili , Applied Organometallic Chemistry (2017) DOI: 10.1002/aoc.3611
[18] L. Buzoglu, E. Maltas, M. Ozmen, S. Yildiz, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 442 (2014) 139.
[19] W. Li, Y. Deng, Z. Wu, X. Qian, J. Yang, Y. Wang, D. Gu, F. Zhang, B. Tu and D. Zhao, Journal of the American Chemical Society, 133 (2011) 15830.
[20] W. Wu, Q. He, Ch. Jiang, Nanoscale Research Letters, 3 (2008) 397.
[21] A. Patel, S. Pathan, Journal of Coordination Chemistry, 65(2012) 3122.
[22] X. Le, Zh. Dong, Zh. Jin, Q. Wang, J. Ma, Catalysis Communications, 53 ( 2014) 47.
[23] H. Salavati, N. Rasouli, Materials Research Bulletin, 46 (2011) 1853.
[24] X. Huang, W. Guo, G. Wang, M. Yang, Q. Wang, X. Zhang, Y. Feng, Zh. Shi, Ch. Li, Materials Chemistry and Physics, 135 (2012) 985.
[25] P. Ferreira, I.S. Goncalves, F.E. Kuhn, A.D. Lopes, M.A. Martins, M. Pillinger, A.Pina, J. Rocha, C.C. Romao, A.M. Santos, T.M. Santos and A.A. Valente, European Journal of Inorganic Chemistry, 10 (2000) 2263.
[26] K. Patel, B. K.Tripuramallu, A. Patel, European Journal of Inorganic Chemistry, (2011) 1871.
[27] S. Pathan, A. Patel, Industrial & Engineering Chemistry Research, 52 (2013) 11913.
[28] X. López,a J.J. Carbó, C. Bo, J. M. Poblet, Chemical Society Reviews, 41 (2012) 7537.
[29] M. Kooti, M. Afshari, Materials Research Bulletin, 47 (2012) 3473.
[30] J. Wang, Y. Zou, Y. Sun, M. Hemgesberg, D. Schaffner, H. Gao, X. Song, W. Zhang, M. Jia, W.R. Thiel, Chinese Journal of Catalysis, 35 (2014) 532.
[31] S.S. Wang, W. Liu, Q.X. Wan, Y. Liu, Green Chemistry, 11 (2009) 1589.
Applied Chemistry Today
Volume 13, Issue 48
September 2018
Pages 181-192

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