Synergistic inhibition effect of thionine and zinc ions on carbon steel corrosion in acidic media

Document Type : Original Article

Authors

1Department of Chemistry and Chemical Engineering, Lamerd Branch, Islamic Azad University, Lamerd, Iran

Abstract

In this research, the inhibition effect of thionine (Thn) and its synergistic effect with Zn2+ on the corrosion of a carbon steel A106 sample in 0.5 M sulfuric acid has been investigated using electrochemical potentiodynamic polarization technique and weight loss tests. Using Tafel polarization plots and corrosion rate calculations, it was revealed that Thn act as an effective inhibitor. It was found that the results of weight loss test and polarization method are in good agreement. The synergistic effect of zinc ions on the corrosion inhibition of steel in the presence of various concentrations of Thn was investigated, too. The addition of zinc ions enhances the inhibition efficiency considerably. Maximum inhibition efficiency was achieved about 97% for a system containing 20 ppm Thn and 16.7 mM Zn2+. The presence of zinc ions increases the degree of surface coverage. The synergism parameters "S", calculated from surface coverage, are found to be larger than unity for some of Thn concentrations. Thn behaved as a mixed type inhibitor in H2SO4 solution. It was investigated too, that the adsorption of Thn on the metal surface was obeyed Langmuir adsorption isotherm and adsorption was performed spontaneously. Investigating the adsorption mechanism proved that it is possible to form a complex between the initial Zn2+ layer on the steel surface with the protonated form of thionine.

Keywords


[1] M. El Faydy, M. Galai, A. El Assyry, A. Tazouti, R. Touir, B. Lakhrissi and M. Ebn Touhami, Journal of Molecular Liquids, 219 (2016) 396.
[2] M. Goyal, S. Kumar, I. Bahadur, C. Verma and E.E. Ebenso, Journal of Molecular Liquids, 256 (2018) 565.
[3] F. Atabaki, Sh. Jahangiri, Journal of Applied Chemistry, 41 (2017) 67.
[4] D. Thirumoolan, V.A. Katkar, G. Gunasekaran, T. Kanai and K.A. Basha, Progress in Organic Coatings, 77 (2014) 1253.
[5] B. Zerga, B. Hammouti, M. Ebn Touhami, R. Touir, M. Taleb, M. Sfaira, M. Bennajeh and I. Forssal, International Journal of Electrochemical Science, 7 (2012) 471.
[6] S.H. Kumar and S. Karthikeyan, Journal of Materials and Environmental Science, 3 (2012) 925.
[7] F. Davoodi and I. Danaee, Journal of Applied Chemistry, 47 (2018) 45, in Persian.
[8] R. Solmaz, Corrosion Science, 79 (2014) 169.
[9] R. Fuchs-Godec and G. Miomir, Pavlovic, Corrosion Science, 58 (2012) 192.
[10] X. Li, S. Deng, H. Fu and G. Mu, Corrosion Science, 52 (2010) 1167.
[11] A.A. Farag and M.A. Hegazy, Corrosion Science, 74 (2013) 168.
[12] S.A. Umoren and M.M. Solomon, Journal of Environmental Chemical Engineering, 5 (2017) 246.
[13] J. Hu, D. Huang, G.L. Song, X. Guo, Corrosion Science, 53 (2011) 4093.
[14] F. Baghaei Ravari, A. Dadgareenezhad, Journal of Chilean Chemical Society, 58 (2013) 1853.
[15] N. Asadi, R. Naderi, M. Mahdavian, Progress in Organic Coatings, 132 (2019) 29.
[16] Z. Sanaei, T. Shahrabi, B. Ramezanzadeh, Dyes and Pigments, 139 (2017) 218.
[17] M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, Z. Sanaei, Journal of Industrial and Engineering Chemistry, (2019), https://doi.org/10.1016/j.jiec.2019.04.056.
[18] L.B. Tang, G.N. Mu and G.H. Liu, Corrosion Science, 45 (2003) 2251.
[19] L.B. Tang, X.M. Li, N. Li, Q. Qu, G.N. Mu and G.H. Liu, Materials Chemistry and Physics, 94 (2005) 353.
[20] E.E. Oguzie, C. Unaegbu, C.N. Ogukwea, B.N. Okolue and A.I. Onuchuku, Materials Chemistry and Physics, 84 (2004) 363.
[21] E.E. Ebenso and E.E. Oguzie, Materials Letters, 59 (2005) 2163.
[22] A.I. Onen1, O.N. Maitera1, J. Joseph1 and E.E. Ebenso, International Journal of Electrochemical Science, 6 (2011) 2884. 
[23] E.E. Oguzie, Materials Chemistry and Physics, 87 (2004) 212.
[24] E.E. Oguzie and E.E. Ebenso, Pigment & Resin Technology, 35 (2006) 30.
[25] E.E. Oguzie, G.N. Onuoha and A.I. Onuchuku, Materials Chemistry and Physics, 89 (2005) 305.
[26] E.E. Oguzie, Materials Letters, 59 (2005) 1076.
[27] E. Oguzie, C. Akalezi and C. Enenebeaku, Pigment & Resin Technology, 38 (2009) 359.
[28] E.E. Oguzie, V.O. Njoku, C.K. Enenebeaku, C.O. Akalezi and C. Obi, Corrosion Science, 50 (2008) 3480.
[29] J. Sathiyabama, S. Rajendran, J.A. Solvi and A.J. Amalraj, Indian Journal of Chemical Technology, 15 (2008) 462.
[30] E.E. Ebsenso, H. Alemu, S.A. Umoren and I.B. Obot, International Journal of Electrochemical Science, 3 (2008) 1325.
[31] X. Li, S. Deng and H. Fu, Corrosion Science, 52 (2010) 3413.
[32] S.D. Deng, X.H. Li, H. Fu, Journal of Applied Electrochemistry, 40 (2010) 2107.
[33] S. Deng, X. Li and H. Fu, Corrosion Science, 53 (2011) 3596.
[34] S. Deng, X. Li and H. Fu, Corrosion Science, 53 (2011) 760.
[35] J. E. Bringas, Handbook of Comparative World Steel Standards, 3rd Edition, ASTM International Publication, (2004).
[36] A. Poursaee, Cement and Concrete Research, 40 (2010) 1451.
[37] S.C. Sahu, A.K. Samantara, M. Seth, S. Parwaiz, B.P. Singh, P.C. Rath and B.K. Jena, Electrochemistry Communication, 32 (2013) 22.
[38] M. Behpour, S.M. Ghoreishi, N. Soltani, M. Salavati-Niasari, M. Hamadanian and A. Gandomi, Corrosion Science, 50 (2008) 2172.
[39] N.A. Negm, N.G. Kandile, E.A. Badr and M.A. Mohammed, Corrosion Science, 65 (2012) 94.
[40] M. Bouklah, B. Hammouti, A. Aouniti, M. Benkaddour, A. Bouyanzer, Applied Surface Science, 252 (2006) 6236.
[41] Peter C. Okafor, Yugui Zheng, Corrosion Science, 51 (2009) 850.
[42] R.Saratha, V.G. Vasudha, E-Journal of Chemistry, 6 (2009) 1003.
[43] E.S. Ferreira, C. Giancomelli, F.C. Giacomelli and A. Spinelli, Materials Chemistry and Physics, 83 (2004) 129.
[44] W.H. Li, Q. He, C.L. Pei and B.R. Hou, Journal of Applied Electrochemistry, 38 (2008) 289.
[45] F. Bentiss, M. Lebrini and M. Lagreneé, Corrosion Science, 47 (2005) 2915.
[46] X. Wang, H. Yang, F. Wang, Corrosion Science, 52 (2010) 1268.
[47] S. Garai, S. Garai, P. Jaisankar, J.K. Singh and A. Elango, Corrosion Science, 60 (2012) 193.
[48] A.Y. Musa, A.B. Mohamad, A.A. H. Kadhum, M.S. Takriff and L.T. Tien, Corrosion Science, 53 (2011) 3672.
[49] U.M. Eduok, S.A. Umoren and A.P. Udoh, Arabian Journal of Chemistry, 5 (2012) 325.
[50] F. Bentiss, M. Traisnel and M. Lagrenee, Corrosion Science, 42 (2000) 127.