Synthesis, Characterization and Determination of the Crystal Structure of New Cadmium Coordination Polymers Based on Bridging Schiff-Base Pyridine Ligand; Investigation of Hirshfeld Surface Analysis

Document Type : Original Article

Authors

Department of Inorganic Chemistry and Catalysis, Faculty of Chemistry Sciences and Petroleum, Shahid Beheshti University, General Campus, Evin, Tehran 1983963113, Iran

Abstract

Two new polymeric compounds of cadmium acetate and Schiff-base ligand 1,2-bis(1-(pyridine-4-yl)ethylydine)hydrazine, L, [Cd(OAc)2(L)]n ,(1) and [Cd(OAc)2(L)(H2O)]n , (2) were synthesized and characterized by single crystal X-ray diffraction analysis. Structural analysis reveals that both compounds were crystallized in monoclinic crystal system with P21/c and I2/a space group respectively. Coordination polymer 1 was synthesized by solvent evaporation method in dimethyl sulfoxide and has one-dimensional ladder like structure. Coordination polymer 2 was prepared by solvent diffusion method in the mixture of methanol and water solvent and its crystal structure was assembled from one-dimensional linear chains. Also the influence of effective interactions in the crystal packing of prepared compounds and the value of their contributions were investigated by Hirshfeld surface analysis.

Keywords

References

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Applied Chemistry Today
Volume 15, Issue 55
June 2020
Pages 95-110

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