catalytic applications of coated nanopalladium particles coated on modified GO by Thymbraspicata extract in Suzuki coupling reactions

Document Type : Original Article

Authors

1 Department of Chemistry, School of Medicinal Chemistry, Tehran University of Medical Sciences, Tehran, Iran

2 Department of Chemistry, Imam Khomeini Memorial Unit, Rey, Islamic Azad University, Tehran, Iran

3 Department of Chemistry, Faculty of Basic Sciences, Payame Noor University, Tehran, Iran

4 Hakim Sabzevari University, Sabzevar

Abstract

In this research coated palladium nanoparticles was synthesized on modified GO by thymbraspicata extract with simple and green procedure and used as adequate and renewable nanocatalyst for Suzuki coupling reactions between phenylboronic acid and different aryl halides. The Pd NPs/RGO Nanocatalyst was synthesized by surface modification of GO and in-Situ reduction. The extract of Thymbraspicata was used as a reducing and immobilizing agent for Pd nanoparticles. The results show that Pd(0) nanoparticles are completely dispersed on the GO functionalized surface. Pd NPs/RGO nanocatalyst as a recoverable nanocatalyst shows high catalytic activity in Suzuki coupling reaction. In addition, the synthesized catalyst can be reused several times without significant altering its catalytic activity.

Keywords

References

[1] A. Balanta, C. Godard, C. Claver, Chem. Soc. Rev. 40 (2011) 4973.
[2] S. Kotha, K. Lahiri, D. Kashinath, Tetrahedron. 58 (2002) 9633.
[3] R.K. Borah, A. Mahanta, A. Dutta, U. Bora, A.J. Thakur,Appl. Organomet. Chem. 31 (2017) e3784.
[4] R. Jana, T.P. Pathak, M.S. Sigman, Chem. Rev. 111 (2011) 1417.
[5] P. Gautam, M. Dhiman, V. Polshettiwar, B.M. Bhanage, Green Chem. 18 (2016) 5890.
[6] a) H. Veisi, M. Ghorbani, S. Hemmati, Mat. Sci. Eng. C 98 (2019) 584 ; b) H. Veisi, P. Safarimehr, S. Hemmati, Mat. Sci. Eng. C 96 (2019) 310.
[7] MR. Yadav, M. Nagaoka, M. Kashihara, RL. Zhong, T. Miyazaki, S. Sakaki, Y. Nakao, J. Am. Chem. Soc. 139 (2017) 9423.
[8] (a) M. Cametti, Z. Dzolic, Chem. Commun. 50 (2014) 8273–8286; (b) M. Liu, R. Zhang, W. Chen, Chem. Rev., 114(2014) 10, 5117; (c) C. Zhang, R. Zhang, S. He, L. Li, X. Wang, M. Liu, W. Chen, ChemCatChem, 96 (2017) 980.
[10] P. Avouris, Graphene: electronic and photonic properties and devices, Nano Lett. 10 (2010) 4285.
[11] C. Noguez, I.L. Garzon, Chem. Soc. Rev. 38 (2009) 757.
[12] J.D. Roy-Mayhew, I.A. Aksay, Chem. Rev. 114 (2014) 6323.
[13] J. Liu, M. Durstock, L. Dai, Energy Environ. Sci. 7 (2014) 1297.
[14] F. Yavari, N. Koratkar, J. Phys. Chem. Lett. 3 (2012) 1746.
 [15] (a) L. Rashidzadeh, A. Noorbakhsh, J. Of Applied Chemistry, 48 (1397) 310, in Persian ; (b) Z. Wang, C. Xu, X.Li, Z. Liu,Colloids and Surfaces A: Physicochem. Eng. Aspects 485 (2015) 102.
[16] M. Hamzelooian, K. Ghasemi, F. Soleimanian, J. Of Applied Chemistry, 52 (1398) 103, in Persian. 
[17] a) Z. Wang, C. Xu, M. Zhao, C. Zhao, RSC Adv. 4 (2014) 47021. ; b)Hemmati S, Mehrazin L, Ghorban H, Garakani SH, Mobaraki TH, Mohammadi P, Veisi H. RSC Adv., 8 (2018) 21020.
[18] S. Shi, F. Chen, E.B. Ehlerding, W. Cai, Bioconjug. Chem. 19 (2014)2033.
[19] J. Ando, T. Yano, K. Fujita, S. Kawata, Phys. Chem. Chem. Phys. 15 (2013) 13713.
[20] P.V. Kamat, J. Phys. Chem.Lett. 1 (2010) 520.
[21] S.I. El-Hout, S.M. El-Sheikh, H.M.A. Hassan, F.A. Harraz, I.A. Ibrahim, E.A. El-Sharkawy, Appl. Catal., A: Gen. . 503 (2015) 176.
[22]H. Veisi, T. Tamoradi, B. Karmakar, P. Mohammadi, S. Hemmati, Mat. Sci. Eng. C,  104 (2019) 109919.
[23] (a) M. Shahriary, H. Veisi, M. Hekmati, S. Hemmati, Mat. Sci. Eng. C. 90 (2018) 57; (b)S Abbasi, M Hekmati, Applied Organometallic Chemistry 2017, 31 (5) e3600
[24] F. R. Fortea, Pérez, I. Schlegel, M. Julve, D. Armentano, G. De Munno, S. E. Stiriba, J.Organomet.Chem. . 743 (2013) 102.
[25] Q. X. Liu, W. Zhang, X. J. Zhao, Z. X. Zhao, M. C. Shi, X. G. Wang, Eur. J. Org.
Chem. . (2013) 1253  .
[26] M. Ghiaci, M. Zargani, F. Moeinpour, A. khojastehnezhad, Appl. Organometal.Chem. . 28 (2014) 589.
[27] V. I. de Paula, C. A. Sato, R. Buffon, J. Braz. Chem. Soc. . 23 (2012) 258.
[28] S. M. ShakilHussain, M. B. Ibrahim, A. Fazal, R. Suleiman, M. Fettouhi, B. El Ali, Polyhedron, 70 (2014) 39.
[29] S. Sobhani, M. S. Ghasemzadeh, M. Honarmand, F. Zarifi, RSC Adv. . 4 (2014) 44166. 
[30] S. Sobhani, F. Zarifi, Chinese J. Catal. (2015) 555.
Applied Chemistry Today
Volume 16, Issue 58
April 2021
Pages 233-244

Files

Share

How to cite

Statistics