An efficient and mild method for the preparation of primary carbamate from alcohols and phenols using sodium cyanate and Boc-protection of amine in the presence of H2SO4-Silica was demonstrated. The reactions were carried out under solvent free conditions. These methods are simple, effective and environmentally friendly and have the advantage of good to excellent yields.
Pourmousavi, S. A., & Hasani, M. (2014). Phosgene-free preparation of primary carbamates and Boc-protection of amine using H2SO4-Silica under solvent free conditions. Applied Chemistry Today, 9(31), 45-60. doi: 10.22075/chem.2017.670
MLA
Seied Ali Pourmousavi; Maryam Hasani. "Phosgene-free preparation of primary carbamates and Boc-protection of amine using H2SO4-Silica under solvent free conditions", Applied Chemistry Today, 9, 31, 2014, 45-60. doi: 10.22075/chem.2017.670
HARVARD
Pourmousavi, S. A., Hasani, M. (2014). 'Phosgene-free preparation of primary carbamates and Boc-protection of amine using H2SO4-Silica under solvent free conditions', Applied Chemistry Today, 9(31), pp. 45-60. doi: 10.22075/chem.2017.670
VANCOUVER
Pourmousavi, S. A., Hasani, M. Phosgene-free preparation of primary carbamates and Boc-protection of amine using H2SO4-Silica under solvent free conditions. Applied Chemistry Today, 2014; 9(31): 45-60. doi: 10.22075/chem.2017.670
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