Synthesis of New Lanthanide Phosphorescent Pigments from Precursor Na[Ln(edta)(H2O)n] (Ln = Dy, Ho, Yb and Er, n = 1-3) Immobilized on B2O3 /Al2O3 bed

Document Type : Original Article

Authors

1 Department of Chemistry, Estahban Higher Education Center, Estahban 74519-44655, Iran

2 Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran

Abstract

Na[Ln(edta)(H2O)n] (Ln = Dy, Ho, Yb and Er, n = 1-3) complexes were synthesized using lanthanide salts and Na4(edta). The synthesized lanthanide complexes were characterized using different techniques including elemental analysis, UV-Vis, FT-IR and fluorescence spectroscopy. Their structures were also optimized using DFT method. Then, the complexes were refluxed in the presence of a mixture of Al(OH)3 and H3BO3 for 24 h. The reaction mixture was then calcined at 400°C for 5 h. The obtained powder as a new phosphorescent pigment was dispersed in water and acrylicpolyurethane resin, and new phosphorescent pigments were finally prepared by adding different percentages of lanthanide oxides to the original pigment. The prepared phosphorescent pigments were investigated using XRD, XRF, and solid state phosphorescence spectroscopy.

Keywords

References

[1] S. K. Zand, S. Baghshahi, M. Rajabi, J. Mater. Sci. 27 (2016) 12533.
[2] E. Karacaoglu, B. Karasu, Mater. Res. Bull. 48 (2013) 3702.
[3] S. Shionoya, W. M. Yen, H. Yamamoto, Phosphor Handbook. CRC Press (2006).
[4] A. Siggel, T. Potrawa, H. Langheim, Patent Application CN19998002369 19990122.
[5] K. L. Haas, K. J. Franz, Chem. Rev. 109 (2009) 4921.
[6] E. Huskowska, I. Turowska-Tyrk, J. Legendziewicz, J. P. Riehl, New J. Chem. 26 (2002) 1461.
[7] M. Salehi, R. Abdoos, B. Bahramian, J. of Applied Chemistry 12 (2018) 99.
[8] M. Nazemian, D. Sanavi Khoshnood, R. Sanavi Khoshnood, J. of Applied Chemistry 34 (1394) 83, in Persian.
[9] G. Buxbaum, Industrial Inorganic Pigments. John Wiley & Sons (2008).
[10] E. G. Moore, A. P. S. Samuel, K. N. Raymond, Acc. Chem. Res. 42 (2009) 542.
[11] R. E. Rojas-Hernandez, M. A. Rodriguez, J. F. Fernandez, RSC Adv. 5 (2015) 3104.
[12] S. K. Yesilay, B. Karasu, E. Karacaoglu, The Proceeding Book of the 15th International Metallurgy and Materials Congress (2010) 2140.
[13] F. Clabau, X. Rocquefelte, S. Jobic, P. Deniard, M. H. Whangbo, A. Garcia, T. Le Mercier, Solid State Sci. 9 (2007) 608.
[14] Z. Wu, M. Gong, J. Shi, Q. Su, J. Alloys Compd. 458 (2008) 134.
[15] Z. Wu, J. Shi, J. Wang, M. Gong, Q. Su, J. Mater. Sci. Mater. Electron. 19 (2008) 339.
[16] A. Ramezanzade Noshabadi, M. H. Ehsani, J. of Applied Chemistry 56 (1399) 313, in Persian.
[17] R. E. G. Frota, A. Spinelli, R. S. da Silva, N. R. da S. Souza, J. A. Junkes, V. P. Della, Ceram. Int. 41 (2015) 5005.
[18] Jr, J. D. Ingle, S. R. Crouch, Spectrochemical Analysis. Prentice Hall (1988).
[19] A. N. Gusev, M. Hasegawa, T. Shimizu, T. Fukawa, S. Sakurai, G. A. Nishchymenko, V. F.Shul’gin, S. B. Meshkova, W. Linert, Inorg. Chim. Acta 406 (2013) 279.
[20] G. L. Law, T. A. Pham, J. Xu, K. N. Raymond, Angew. Chem. Int. Ed. 51 (2012) 2371.
[21] E. F. Kustov, G. A. Bandurkin, E. N. Murav’ev, V. P. Orlovskii, Electronic Spectra of Compounds of Rare-Earth Elements. Mocsow (1981).
[22] P. Martn-Ramos, M. R. Silva, F. Lahoz, I. R. Martn, P. Chamorro-Posada, M. E. S. Eusebio, V. Lavn, J. Martn-Gil, J. Photochem. Photobiol., A 292 (2014) 16.
[23] R. A. Talewar, S. Mahamuda, K. Swapna, A. S. Rao, J. Alloys Compd. 771 (2019) 980.
[241] L. Samain, A. Jaworski, M. Edén, D. M. Ladd, D. K. Seo, F. J. Garcia-Garcia, U. Häussermann, J. Solid State Chem. 217 (2014) 1.
[25] S. Y. Kaya, E. Karacaoglu, B. Karasu, Adv. Appl. Ceram. 111 (2012) 393.
[26] S. Y. Kaya, B. Karasu, Ceram. Int. 38 (2012) 2757.
Applied Chemistry Today
Volume 17, Issue 64
September 2022
Pages 71-88

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