The synthesis of Fe3O4/SiO2/TiO2/CoIIITHPP magnetic nanocomposite as catalyst in reaction of luminol-H2O2 chemiluminescence system

Document Type : Original Article

Authors

1 Department of Inorganic Chemistry, University of Mazandaran, Babolsar, Mazandaran, Iran

2 Department of Analytical Chemistry, University of Mazandaran, Babolsar, Mazandaran, Iran

Abstract

The luminol chemiluminescent reaction is among well-known quantitative methods in analytical spectroscopy due to its high sensitivity to presence of catalyst and low background signal. In this study, magnetic nanocomposite of Fe3O4/SiO2/TiO2/CoIIITHPP (THPP : tetrahyroxyphenylporphyrin) has been synthesized by co-precipitation method and characterized with fourior transform-infrared (FT-IR), X-ray photoelectron spectroscopy (XRD), vibrating sample magnetometer (VSM), scanning electron microscope (SEM), trasmiddion electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS. For the fist time, this magnetic nanocomposite has been used as catalyst of chemolumincence reactions and showed high catalytic effect on the luminol-H2O2 system. The recovery of catalyst was easily performed by applying the external magnetic field.

Keywords

Main Subjects

This is an open access article under the CC-BY-SA 4.0 license.( https://creativecommons.org/licenses/by-sa/4.0/)

References

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Applied Chemistry Today
Volume 18, Issue 67
June 2023
Pages 91-106

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