Preparation of low-cost and porous WO3/CNTs-Graphite-PVC films with high mechanical strength for application as bioanode in microbial fuel cell

Document Type : Original Article

Authors

Electrochemistry Research Laboratory, Department of Physical Chemistry, Chemistry Faculty, Urmia University, Urmia, Iran

Abstract

A microbial fuel cell (MFC) is a device that converts chemical energy into electrical energy through the catalytic processes of microorganisms. In this study, flexible and porous WO3/CNTs-Graphite-PVC film was fabricated through uniform adding of Zn powder into matrix of carbon nanotubes-graphite- Polyvinyl Chloride) PVC (film followed by selective dissolving of Zn from the film structure in acidic solution and finally electrodeposition of WO3 (Tungsten trioxide) into previously porous CNTs-Graphite-PVC film. Surface morphology studies showed that the flexible film has rough and porous structure and carbon nanotubes are uniformly present as electron conduction channels within the composite film. Studies also showed that porous WO3/MWCNTs-Graphite-PVC film as a bioanode in MFC at resistance of 1000 ohms and current density of 900 mA/m2 has a power density of 324 mW/m2. The method presented in this research can be used as a suitable method for preparing of suitable electrocatalysts based on commercial graphite powder in microbial fuel cells.

Keywords

Main Subjects


This is an open access article under the CC-BY-SA 4.0 license.( https://creativecommons.org/licenses/by-sa/4.0/)

[2] Yaqoob, A.A., Mohamad Ibrahim, M.N., & Rodríguez-Couto, S.  (2020). Development and modification of materials to build cost-effective anodes for microbial fuel cells (MFCs): An overview. Biochemical Engineering Journal, 164, 107779.
[6] Picot, M., Lapinsonnière, L., Rothballer, M., & Barrière, F.  (2011). Graphite anode surface modification with controlled reduction of specific aryl diazonium salts for improved microbial fuel cells power output. Biosensors and Bioelectronics 28, 181-188.
[7] González, T. , Ureta-Zañartu, M.S., Marco, J.F., &Vidal, G.  (2019). Effect of Zeolite-Fe on graphite anode in electroactive biofilm development for application in microbial fuel cells. Applied Surface Science, 467–468, 851-859.
[9] Xu, H., Wang, L., Wen, Q., Chen, Y., Qi, L., Huang, J., & Tang, Z.  (2019).  A 3D porous NCNT sponge anode modified with chitosan and Polyaniline for high-performance microbial fuel cell. Bioelectrochemistry, 129, 144-153.
[10] Silva, T.C.A., Bhowmick, G.D., Ghangrekar, M.M., Wilhelm, M., & Rezwan K. (2019).   SiOC-based polymer derived-ceramic porous anodes for microbial fuel cells. Biochemical Engineering Journal, 148, 29-36.
[11] Li, X., Tang, Y., Song, J., Yang, W., Wan, M., Zhu, C., Zhao, W., Zheng, J., & Lin, Y., (2018). Self-supporting activated carbon/carbon nanotube/reduced graphene oxide flexible electrode for high performance supercapacitor. Carbon, 129, 236-244.
[12] Ramesh, S., & Yi, L.J. (2009). FTIR spectra of plasticized high molecular weight PVCLiCF3SO3 electrolytes. Ionics, 15,413-420.
[13] Da Silva, M.A., Vieira, M.G.A., Maçumoto, A.C.G., Beppu, M.M. (2011). Polyvinylchloride (PVC) and natural rubber films plasticized with a natural polymeric plasticizer obtained through polyesterification of rice fatty acid. Polymer Testing, 30, 478-484.
[16] Sayed, E.T., Abdelkareem, M.A., Alawadhi, H., Elsaid, K., Wilberforce, T., Olabi, A.G. (2021). Graphitic carbon nitride/carbon brush composite as a novel anode for yeast-based microbial fuel cells.
Energy, 221, 119849.