Solid Phase Degradation Study on Polyethylene-Rhodamine B Composite under UV light

Document Type : Original Article

Abstract

    In the present work, Polyethylene- Rhodamine B composites at various concentration of Rhodamine B dye in 200 µm thickness were fabricated. Various influencing concepts like radiation time and concentration on photodegradtion of Rhodamine B in solid state was investigated. The oxidation was studied by FT-IR spectroscopy and it was shown that the oxidation products consisting carbonyl group are obtained. All samples exhibited significant changes in color with exposure conditions. Results indicated that the photodegradation efficiency was increased by rising radiation intensity, dye concentration and time of exposure. Also, it was showed that the photodegradation kinetics obeys a first-order kinetic model.

Keywords


[1] J.V. Gulmine , P.R. Janissek  , H. M. Heise, L. Akcelrud, Polymer Degradation and Stability, 79 (2003) 385.
[2] D. Briassoulis, A. Aristopoulou, M. Bonora, I. Verlodt, Biosystems Engineering, 88 (2004)131.
[3] D. Briassoulis Polymer Degradation and Stability, 91 (2006) 1256.
[4] G. Scarascia, E. Schettini, G. Vox, M. Malinconico, B. Immirzi, S. Pagliara, Polymer Degradation and Stability, 91(2006) 2801.
[5] C.R. Yan, X.R. Mei, W.Q. He, Trans. CSAE, 22 (2006) 269.
[6] Leos, Vasek, Bachelor Thesis, Tomas Bata University in Zlin Faculty of Technology, (2006).
[7] S.H. Kim, S.Y. Kwak, T. Suzuki, Polymer, 47 (2006) 3005.
[8] S. Chakrabarti, B. Chaudhuri, S. Bhattacharjee, P. Das, B.K. Dutta, Journal of Hazardous Materials, 22 (2007) 428.
[9] J. Shang, M. Chai, Y.F. Zhu, Journal of Solid State Chemistry, 174 (2003) 104.
[10] X. Zhao, Z. Li, Y. Chen, L. Shi, Y. Zhu, Journal of Molecular Catalysis A: Chemical, 269 (2007) 101.
[11] X. Zhao, Z. Li, Y. Chen, L. Shi, Y. Zhu, Applications of Surface Science, 254 (2007) 1825.
[12] W.J. Fa, L. Zan, C. Gong, J.C. Zhong, K.J. Deng, Applied Catalysis B: Environmental, 79 (2008) 216.
[13] F. Carrasco, P. Pages, S. Pascual, X. Colom, European Polymer Journal, 37 (2001) 1457.
[14] T. Corrales, F. Catalina, C. Peinado, N.S. Allen, E. c. Fontan,  Journal of Photochemistry and
Photobiology A: Chemistry, 147(2002) 213.
[15] I. H. Craig, J. R. White, A.V. Shyichuk, I. Syrotynska, Polymer Engineering & Science, 45 (2005) 579.
[16] L. Guadagno, C. Naddeo, V. Vittoria, G. Camino, Polymer Degradation and Stability, 72 (2001) 175.
[17] A. Valadez-Gonzalez, J. M. Cervantes-Uc, L. Veleva, Polymer Degradation and Stability, 63 (1999) 253.
[18] C. Alfred-Duplan, J. Musso, j. R. Gavarri, C. Cesari, Journal of Solid State Chemistry, 110 (1994) 6.
[19] V. S. Smitha, K. A. Manjumol, S. Ghosh, M. Brahmakumar, C. Pavithran, P. Perumal, K. G. Warrier, Journal of the American Ceramic Society, 94 (2011) 1731.
[20] H. Miyazaki, Y. Teranishi, T. Ota, Solar Energy Materials and Solar Cells, 90 (2006) 2640.

[21] W. Caseri, Chemical Engineering Communications , 196 (2008) 549.

[31] S. Butylina, O. Martikka, T. Karki, Polymer Degradation and Stability, 120 (2015) 10.
[32] Y. Chen, Y. Qi, Z. Tai, X. Yan, F. Zhu, Q. Xue, European Polymer Journal, 48 (2012) 1026.
[33] R. Yang, P. A. Christensen, T. A. Egerton, J. R. White, Polymer Degradation and Stability, 95 (2010) 1533.
[34] B. Elvers, J. F. Rounsaville, G. Schulz, Ulmanns Encyclopedia of Industrial Chemistry,  German, (1988) 279.
[35] A. K. Gustavsson, MSc thesis, Physics of Materials and Biological Systems Radiation Physics, Gothenburg University, March 2010.
[36] A. Mehrdad, B. Massoumi, R. Hashemzadeh, Chemical Engineering Journal, 168 (2011) 1073.
[37] Ch. Guo, J. Xu, Y. He, Y. Zhang, Y. Wang, Applied Surface Science, 257 (2011) 3798.
[38] D. Yu, R. Cai, Zh. Liu, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60 (2004) 1617.
[39] R. Nagaraja, N. Kottam, C.R. Girija, B. M. Nagabhushana, Powder Technology, 91-97 (2012) 215.
[40] L. Douminge, S. Mallarino, S. Chendoz, X. Feaugas, J. Bernard, Current Applied Physics, 10 (2010) 1211.
[41] L. Youji, S. Shuguo, M. Mingyuan, O. Yuzhu, Y. Wenbin, Chemical Engineering Journal, 142 (2008) 147.
[42] K. Vinod, R. Gupta, S. A. Jain, S. Meenakshi, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 378 (2011) 22.
[43] J. Wang, Z. Jiang, L. Zhang, P. Kang, Y. Xie, Y. Lv, R. Xu, X. Zhang, Ultrasonics Sonochemistry, 16 (2009) 225.
[44]  J. Wang,  Z. Jiang, Z. Zhang, Y. Xie, Y. Lv, J. Li, Y. Deng, X. Zhang, Separation and Purification Technology, 67 (2009) 38.
[45] F. H. AlHamedi, M. A. Rauf, S. S. Ashraf, Desalination, 239 (2009) 159