شیمى کاربردى روز

شیمى کاربردى روز

سنتز و شناسایی نانوکامپوزیت Fe/Quasi MOF UIO-66 (Zr) به منظور حذف رنگزای متیلن بلو از محلول آبی آن و بررسی مدل های سینتیک

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
1 پژوهشکده علوم و فناوری نانو، دانشگاه کاشان، کاشان، ایران
2 گروه شیمی، دانشکده علوم پایه، دانشگاه اراک، اراک، ایران
چکیده
در این پژوهش، نانوکامپوزیت Fe/Quasi MOF UIO-66 (Zr) سنتز شده به روش اولتراسونیک برای حذف رنگ متیلن بلو از محلول آبی مورد استفاده قرار گرفت. خواص فیزیک شیمیایی و مورفولوژی نانوکامپوزیت سنتز شده توسط آنالیزهای مختلف شامل XRD، FTIR، SEM، TGA و BET شناسایی شد. فعالیت فوتوکاتالیستی نانوکامپوزیت برای حذف رنگزای متیلن بلو بررسی شد و اثر عوامل مختلف شامل مقدار جاذب، pH، غلظت اولیه رنگ، زمان تماس و دما بررسی شد. سینتیک فرایند حذف با استفاده از مدل های شبه مرتبه اول، شبه مرتبه دوم و نفوذ درون ذره ای ارزیابی گردید. نتایج نشان داد که مقدار بهینه جاذب 045/0 گرم بوده و بیشترین راندمان حذف در شرایط قلیایی حاصل می شود. بررسی سینتیکی نشان داد اگرچه هر دو مدل تطابق مناسبی با داده ها دارند، مدل شبه مرتبه دوم دارای ضریب همبستگی بالاتری است که نشان دهنده غالب بودن مکانیزم جذب می باشد. نتایج آنالیزهای مختلف تشکیل موفق نانوکامپوزیت و ساختار نانومقیاس آن را تایید کرد.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Synthesis and characterization of Fe/Quasi MOF UIO-66 (Zr) nanocomposite for the removal of methylene blue dye from its aqueous solution and investigation of kinetic models

نویسندگان English

Ali Safari 1
Ahmad Akbari 1
Farhad Heidary 2
1 Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran
2 Department of Chemistry, Faculty of Basic sciences, Arak University, Arak, Iran
چکیده English

In this study, a Fe/Quasi MOF UIO-66 (Zr) nanocomposite synthesized via ultrasonic method was applied for the removal of methylene blue dye from aqueous solution. Physico-chemical and morphological properties of as-fabricated nanocomposites characterized by several methods including x-ray diffraction (XRD), fourier transform-infrared spectroscopy (FT-IR), scanning electron microscopy (FE-SEM), and N2 gas absorption/desorption analysis or Brunauer-Emmett-Tellers (BET). The photocatalytic activity of nanocomposite was investigated against Methylene blue dye and the effects of catalyst dosage, pH, initial dye concentration, contact time and temperature were investigated. Adsorption kinetics were evaluated using pseudo-first order, pseudo-second order and interparticle diffusion models. The results showed that the optimal adsorbent dosage was 0.045 g and alkaline conditions (pH=11) led to the highest removal efficiency. Kinetic analysis indicated that although both kinetic models fitted the experimental data well, the pseudo-second order model exhibited a higher correlation coefficient, suggesting that adsorption is the dominant mechanism. Different analyses confirmed the successful synthesis and nanoscale structure of the Fe/Quasi UIO-66 composite.

کلیدواژه‌ها English

Methylene blue dye
metal-organic framework
removal kinetics
[1] Zheng, J., et al., Universal Strategy for Metal‐Organic Framework Growth: From Cascading‐Functional Films to MOF‐on‐MOFs (Small 34/2024). Small, 2024. 20.
[2] Hayat, A., et al., Recent Advance in MOFs and MOF-based Composites: Synthesis, Properties, and Applications. Materials Today Energy, 2024. 41: p. 101542.
[3] Yaxiong, J., et al., Engineering metal organic framework (MOF)@MXene based electrodes for hybrid supercapacitors – A review. Chemical Engineering Journal, 2024. 483: p. 149365.
[4] Ali, A., et al., Synthesis Method of Stable Metal-Organic Framework (MOF) Based Nanomaterials and Their Multifaceted Application. 2024. 11: p. 361-386.
[5] Falcaro, P., (Invited) Progress in 3D-Oriented MOF Systems. ECS Meeting Abstracts, 2024. MA2024-02: p. 2496-2496.
[6] Masoomi, M., et al., Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design. Angewandte Chemie International Edition, 2019. 58.
[7] Adams, T., et al., Water Adsorption Capacity of UiO-66 Metal Organic Framework (MOF) Nanoparticles for Applications in Water Harvesting. 2024.
[8] Del, M., M. Molina González, and C. García Lirios, WATER SUSTAINABILITY IN THE LITERATURE FROM 2020 TO 2024. 2024.
[9] Dhanasekaran, N.C., Water Scarcity- Challenging the Future. International Journal of Agriculture Environment and Biotechnology, 2019. 12.
[10] Baba, D., Water Pollution: Causes, Impacts, and Solutions: a critical review. 2024: p. 1-18.
[11] Emran, I., et al., Reasons behind the Water Crisis and its Potential Health Outcomes. 2024.
[12] El-Sayed, E., et al., Azo dyes: Synthesis, Classification and Utilisation in Textile Industry. Egyptian Journal of Chemistry, 2024.
[13] Ghafoor, S., et al., Evaluation of azo dyes degradation potential of Aspergillus strains: A strategy for waste management. Journal of Hazardous Materials Advances, 2024. 16: p. 100475.
[14] Alsantali, R., et al., Miscellaneous azo dyes: A comprehensive review on recent advancements in biological and industrial Applications. Dyes and Pigments, 2021. 199: p. 110050.
[15] Akter, F. and Y. Dong, Investigation of removing orange II azo dye from wastewater through an oxidation process. Applied Water Science, 2024. 14.
[16] Digamber, S. and S. Tupare, Versatility of Azo Dyes : A Short Review. 2024.
[17] Ghosh, N., et al., Adsorption and Desorption Study of Reusable Magnetic Iron Oxide Nanoparticles Modified with Justicia adhatoda Leaf Extract for the Removal of Textile Dye and Antibiotic. Water, Air, & Soil Pollution, 2023. 234(3): p. 202.
[18] Chaabna, I., R. Delimi, and R. Testas, Removal of methylene blue using magnetic Na-bentonite composite in aqueous Solutions. Desalination and Water Treatment, 2024. 318: p. 100353.
[19] Zemouri, A.E., et al., Efficient wastewater decontamination using magnetic bentonite-alginate beads: A comprehensive study of adsorption dynamics, regeneration, and molecular interactions. Journal of Environmental Chemical Engineering, 2024. 12(3): p. 113000.
[20] Chauhan, V., et al., Antibiotics contamination in the environment and its remediation. 2024. p. 157-170.
[21] Yang, C., B. Cai, and K. Chong, Environmental antibiotic pollution and resistance in China: pollution status, degradation methods and control strategies. The International Journal of Learner Diversity and Identities, 2024. 31: p. 471-484.
[22] Katz, M.J., et al., A facile synthesis of UiO-66, UiO-67 and their derivatives. Chemical Communications, 2013. 49(82): p. 9449-9451.
[23] Mair, P., et al., Laser powder bed fusion of nano-CaB6 decorated 2024 aluminum alloy. Journal of Alloys and Compounds, 2021. 863: p. 158714.
[24] Rafiu, R., X-ray Diffraction (XRD) analysis. 2024.
[25] Payam, A.F., S. Khalil, and S. Chakrabarti, Synthesis and Characterization of MOF‐Derived Structures: Recent Advances and Future Perspectives. Small, 2024. 20: p. e2310348.
[26] Wang, Y.L., et al., UiO-66-based metal organic frameworks for the photodegradation of acetaminophen under simulated solar irradiation. Journal of Environmental Chemical Engineering, 2021. 9(5): p. 106087.
[27] Monshi, A., M.R. Foroughi, and M. Monshi, Modified Scherrer Equation to Estimate More Accurately Nano-Crystallite Size Using XRD. World Journal of Nano Science and Engineering, 2012. 2: p. 154-160.
[28] Leitão Muniz, F., et al., The Scherrer equation and the dynamical theory of X-ray diffraction. Acta Crystallographica Section A, 2016. 72: p. 385-390.
[29] Ghalei, B., et al., Rational Tuning of Zirconium Metal–Organic Framework Membranes for Hydrogen Purification. Angewandte Chemie International Edition, 2019. 58.
[30] Eltaweil, A.S., et al., Fabrication of UiO-66/MIL-101(Fe) binary MOF/carboxylated-GO composite for adsorptive removal of methylene blue dye from aqueous solutions. RSC Advances, 2020. 10(32): p. 19008-19019.
[31] Liu, P., J. Lyu, and P. Bai, One-Step Synthesis of Al-Doped UiO-66 Nanoparticle for Enhanced Removal of Organic Dyes from Wastewater. Molecules, 2023. 28(5): p. 2182.
[32] Kim, H., et al., Controlling the Structural Robustness of Zirconium-Based Metal Organic Frameworks for Efficient Adsorption on Tetracycline Antibiotics. Water, 2021. 13: p. 1869.
[33] Hu, X., et al., Application of a novel adsorbent UiO-66 modified by Ce to tetracycline removal in water bodies. Journal of Environmental Chemical Engineering, 2023. 11(5): p. 110478.
[34] Wang, C., et al., Thermogravimetric analysis (TGA) for characterization of self-cementation of recycled concrete aggregates in pavement. Thermochimica Acta, 2024. 733: p. 179680.
[35] Zorainy, M.Y., et al., Microwave-Assisted Synthesis of the Flexible Iron-based MIL-88B Metal–Organic Framework for Advanced Energetic Systems. Journal of Inorganic and Organometallic Polymers and Materials, 2022. 32.
[36] Xu, W., et al., A Facile Method for Preparing UiO-66 Encapsulated Ru Catalyst and its Application in Plasma-Assisted CO2 Methanation. Nanomaterials, 2019. 9: p. 1432.
[37] Pu, H., et al., Anchoring Au on UiO-66 surface with thioglycolic acid for simultaneous SERS detection of paraquat and diquat residues in cabbage. Microchemical Journal, 2023. 190: p. 108563.
[38] Bell, E., et al., BEaTmap: Simplified Rigorous BET Analysis of Isothermal Adsorption Data. Journal of Open Research Software, 2024. 12.
[39] Davis, M., K. Yan, and Jennifer G. Murphy, Evaluating adsorption isotherm models for determining the partitioning of ammonium between soil and soil pore water in environmental soil samples. Biogeosciences, 2024. 21: p. 5381-5392.
[40] Al-Senani, G. and F. Al-Fawzan, Adsorption study of heavy metal ions from aqueous solution by nanoparticle of wild herbs. The Egyptian Journal of Aquatic Research, 2018. 44.
[41] Mohammed Eldesoky Ahmed, A., toghan-et-al-2024-effect-of-adsorption-and-interactions-of-new-triazole-thione-schiff-bases-on-the-corrosion-rate-of. ACS Omega, 2024. 9.
[42] Hupian, M., et al., Activated carbon treated with different chemical agents for pertechnetate adsorption. Journal of Radioanalytical and Nuclear Chemistry, 2024. 333.
[43] El-Baz, A., et al., Adsorption technique for pollutants removal; current new trends and future challenges -A Review. 2021: p. 1-24.
[44] Wang, Y., et al., Guideline for modeling solid-liquid adsorption: Kinetics, isotherm, fixed bed, and thermodynamics. Chemosphere, 2023. 349: p. 140736.
[45] Musah, M., et al., Adsorption Kinetics and Isotherm Models: A Review. Caliphate Journal of Science and Technology, 2022. 4.
[46] Guo, X. and J. Wang, A general kinetic model for adsorption: Theoretical analysis and modeling. Journal of Molecular Liquids, 2019. 288: p. 111100.
[47] Tan, K.L. and B. Hameed, Insight into the adsorption kinetics models for the removal of contaminants from aqueous solutions. Journal of the Taiwan Institute of Chemical Engineers, 2017. 74.
[48] Sevim, F., et al., Investigation of Adsorption Capacity, Kinetics and Thermodynamics in The Removal of Textile Dye in Wastewater. 2024.
[49] Güneş, K., Isotherm and kinetic modeling of the adsorption of methylene blue, a cationic dye, on pumice. International Journal of Chemistry and Technology, 2023. 7: p. 68-76.
[50] Milonjic, S., A Consideration of the Correct Calculation of Thermodynamic Parameters of Adsorption. Journal of the Serbian Chemical Society, 2007. 72.
[51] Tran, H., Improper estimation of thermodynamic parameters in adsorption studies with distribution coefficient KD (qe/Ce) or Freundlich constant (KF): Conclusions from the derivation of dimensionless thermodynamic equilibrium constant and suggestions. Adsorption Science & Technology, 2022.
[52] Lima, E., et al., A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption. Journal of Molecular Liquids, 2018. 273.