شیمى کاربردى روز

شیمى کاربردى روز

بررسی مقاومت به خوردگی زیرلایه‌های مسی رسوب‌دهی الکتریکی شده با نانوکامپوزیت‌های نیکل-روی-فسفر/بورکربید

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
گروه شیمی، دانشگاه سید جمال الدین اسدآبادی، اسدآباد، ایران
چکیده
در تحقیق حاضر، پوشش‌های نانوکامپوزیتی نیکل-روی-فسفر/بورکربید از طریق رسوب الکتریکی از الکترولیت حاوی غلظت‌های مختلف بورکربید به عنوان ذرات تقویت‌کننده، با استفاده از چگالی جریان بهینه‌شده mA/cm2 50 سنتز شدند. در بررسی‌های بعدی مورفولوژی سطح، ساختار فازی و ترکیب عنصری پوشش‌ها به ترتیب با استفاده از میکروسکوپ الکترونی روبشی (SEM)، پراش اشعه ایکس (XRD) و طیف سنجی پراش انرژی پرتو ایکس (EDS) انجام شد. مقاومت در برابر خوردگی پوشش‌های ساخته شده با استفاده از طیف‌سنجی امپدانس الکتروشیمیایی (EIS)، اندازه‌گیری‌های پتانسیل مدار باز (OCP) و مطالعات پلاریزاسیون تافلی در محلول % NaCl5/3 ارزیابی شد. این بررسی‌ها نشان داد که پوشش‌های کامپوزیتی با سطوحی صاف و یکنواحت، مقاومت در برابر خوردگی بالاتری نسبت به پوشش آلیاژی خالص Ni-P-Zn دارند و کمترین چگالی جریان خوردگی و بالاترین مقاومت در برابر خوردگی برای پوشش تولید شده از محلول حاویg/L 6 از B4C حاصل شده است. همرسوبی در این غلطت بهینه از B4C، ریزساختاری یکنواخت، بدون نقص و متراکم ایجاد کرد و در نتیجه رفتار خوردگی پوشش‌ها را بهبود بخشید.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Investigation of the Corrosion Resistance of Copper Substrates Electrodeposited with Ni-Zn-P/B4C Nanocomposites

نویسندگان English

Saeid Mohammadian Hamraz
Mehdi Abdolmaleki
Younes Hanifehpour
Department of Chemistry, Sayyed Jamaleddin Asadabadi University, Asadabad, Iran
چکیده English

In the present study, nickel-zinc-phosphorus/boron carbide nanocomposite coatings were synthesized via electrodeposition from an electrolyte containing different concentrations of boron carbide as reinforcing particles, using an optimized current density of 50 mA/cm2. In subsequent investigations, the surface morphology, phase structure, and elemental composition of the coatings were conducted using scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDS), respectively. The corrosion resistance of the fabricated coatings was evaluated by electrochemical impedance spectroscopy (EIS), open‑circuit potential (OCP) measurements, and Tafel‑polarization studies in a 3.5 % NaCl solution. These studies demonstrated that composite coatings with smooth and uniform surfaces have higher corrosion resistance than pure Ni-P-Zn alloy coatings, and the lowest corrosion current density and highest corrosion resistance were obtained for the coating produced from a solution containing 6 6 g/L B4C. Co‑deposition at this optimal B4C concentration yielded a uniform, defect‑free, dense microstructure, thereby enhancing the corrosion behavior of the coatings.

کلیدواژه‌ها English

Electrodeposition
Nanocomposite
Ni-Zn-P/B4C
Electrochemical Impedance Spectroscopy
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