نوع مقاله : مقاله علمی پژوهشی
نویسندگان
1 دانشکده شیمی، واحد فیروزکوه، دانشگاه آزاد اسلامی ، فیروزکوه، ایران
2 گروه شیمی، واحدیزد، دانشگاه آزاد اسلامی، یزد، ایران
چکیده
کلیدواژهها
عنوان مقاله [English]
نویسندگان [English]
Silica- supported boron trifluoride nanoparticles (BF3. SiO2 NPs) was prepared and used as a mild green solid acid catalyst for the synthesis of pyrano[2,3-d]pyrimidine derivatives from the reaction of aromatic aldehydes with ethylcyanoacetate and barbituric acid in ethanol. The reaction was efficiently promoted by BF3. SiO2 NPs and the heterogeneous catalyst was recycled for three runs in this reaction without losing its catalytic activity. Reusable and eco-friendly catalyst, simple work up procedure, easy separation of product from reaction mixture, safe and clean reaction giving high yield of the corresponding pyrano[2,3-d] pyrimidine in a short time, are some advantages of this protocol.
کلیدواژهها [English]