نوع مقاله : مقاله علمی پژوهشی
نویسندگان
1 گروه شیمی، واحد تبریز، دانشگاه آزاد اسلامی، تبریز، ایران
2 گروه شیمی، دانشکده علوم، دانشگاه ارومیه، ارومیه، ایران
چکیده
کلیدواژهها
عنوان مقاله [English]
نویسندگان [English]
In this investigation, a novel nano-adsorbent based on magnetic graphene oxide nanocomposite was used for dispersive solid-phase microextraction (D-SPME) of melamine in environmental water samples. The m@GO-RAFT agents were synthesized by surface modification of Fe3O4 nanoparticles with graphene oxide via surface reversible addition-fragmentation chain transfer (RAFT) copolymerization, as characterized by electron microscopy (SEM and TEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and vibrating sample magnetometer (VSM). Several parameters affecting extraction performance, including the extraction solvent, amount of nano-adsorbent, contact time and back-extraction time, and sample pH were evaluated and optimized. Under the optimum conditions, analytical figures of merit such as linearity, limit of detection (LOD) and limit of quantitation (LOQ) were found to be 0.03–100 µg/L, 0.011 µg/L, and 0.027 µg/L, respectively.
کلیدواژهها [English]
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