تهیه نانوجاذب سیلیکاتی SBA-16 به روش سبز از ساقه گیاه نی، استفاده از آن جهت حذف آلاینده فنل-فتالئین و بررسی عوامل موثر به روش RSM

نوع مقاله : مقاله علمی پژوهشی

نویسندگان

گروه شیمی، دانشکده علوم پایه، دانشگاه آیت الله بروجردی، بروجرد، ایران

چکیده

در این کار، نانومزوپوز SBA-16 از ساقه گیاه نی به روش سبز تهیه شد و برای حذف آلاینده فنل فتالئین استفاده گردید. اثر پارامترهای مختلف (pH، غلظت اولیه فنل فتالئین، مقدار جاذب SBA-16، دما و زمان تماس) در میزان جذب فنل فتالئین توسط جاذب تهیه شده، به کمک نرم‌افزار طراحی آزمایش بررسی شد. نتایج حاصل از آزمایش‌های پیش‌بینی شده نشان داد که بالاترین جذب فنل فتالئین در شرایط 01/4=pH، دمای °C 44، زمان تماس min 20، غلظت اولیه جذب شونده mg/L 13 و مقدار جاذب g 05/0 دیده می‌شود. در شرایط بهینه، پیش‌بینی نرم‌افزار حذف 100 درصدی فنل فتالئین از محیط آبی بوده است که عملا میزان حذف 46/99 درصد به دست آمد. با توجه به پتانسیل بالای نانومزوپور SBA-16 در حذف رنگدانه فنل فتالئین، می‌تواند کاندیدای مناسبی در حذف آلاینده‌های رنگی و تصفیه فاضلاب‌های کارخانجات نساجی محسوب شود.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Preparation of SBA-16 silicate nanoabsorbent by green method from reed plant stem, using it to remove Phenolphthalein pollutant and investigating effective factors by RSM method

نویسندگان [English]

  • mohammad hossein fekri
  • fatemeh saki
  • Maryam Razavi-mehr
  • samaneh soleymani
Department of Chemistry, Faculty of Basic Sciences, Ayatollah Borujerdi University, Borujerd, Iran
چکیده [English]

In this work, nanomesopose SBA-16 was prepared from reed plant stem by green method and used to remove Phenolphthalein pollutant. The effect of different parameters (pH, initial concentration of phenolphthalein, amount of SBA-16 adsorbent, temperature and contact time) on the amount of phenolphthalein absorption by the prepared adsorbent was investigated with the help of experiment design software. The results of the predicted experiments showed that the highest absorption of phenolphthalein was in the conditions of pH=4.01, temperature 44°C, contact time 20 min, initial concentration of adsorbent 13 mg/L and amount of adsorbent 0.05 g. can be seen. In optimal conditions, the prediction of the software was 100% removal of phenolphthalein from the water environment, which actually achieved a removal of 99.46%. Considering the high potential of nanomesopore SBA-16 in removing phenolphthalein pigment, it can be considered as a suitable candidate for removing colored pollutants and treating wastewater from textile factories.

کلیدواژه‌ها [English]

  • Nano mesoporous SBA-16
  • Phenolphthalein pigment
  • reed stem
  • green method
  • experimental design

This is an open access article under the CC-BY-SA 4.0 license.( https://creativecommons.org/licenses/by-sa/4.0/)

[1] Dehua, X., Irene, M. C. (2016). Synthesis of magnetically separable Bi2O4/Fe3O4 hybrid nanocomposites with enhanced photocatalytic removal of ibuprofen under visible light irradiation. Water Research.100, 1.
[2] Dunnick, J. K., Hailey, J. R. (1996). Phenolphthalein exposure causes multiple carcinogenic effects in experimental model systems Cancer Res. 56, 4922-4926.
[3] Sayadi Anari, A. R., Asadpour, M., Shabani, Z., Sayadi Anari, M. H. (2013). Pharmaceutical Pollution of the eco-system and Its Detrimental Effects on Public Health. Journal of Rafsanjan University of Medical Sciences. 11, 11-18.
[4] Fekri, M. H., Isanejad Mohamareh, S., Hosseini, M., Razavi Mehr, M. (2022). Green synthesis of activated carbon/Fe3O4 nanocomposite from flaxseed, its application as adsorbent and antibacterial. Chem. Pap. 76, 6767.
[5] Dashti Khavidaki, H., Fekri, M. H. (2015). Removing Thallium (I) Ion from Aqueous Solutions Using Modified ZnO Nanopowder. J. Adv. Chem. 11, 3777.
[6] Dashti Khavidaki, H., Sarlal, F., Fekri, M. H. (2023). Adsorption Characteristics of Amoxicillin on Activated Carbon from Eucalyptus Leave and Wheat Straw. Journal of Applied Chemistry. DOI: 10.22075/chem.2023.26959.2066.
[7] Oliver, A. H., Voulvoulis, N., John, N. L. (2003). Potential impact of pharmaceuticals on environmental health. Bull. W. H. O. 81, 768-769.
[8] Steinnes, E., Anderson, E. (1991). Atmosperic deposition of mercury in Norway: temporal and spatial trends. Water, Air, Soil Pollut. 56, 391-404.
[9] Fekr, M. H., Shahverdi, V., Chegeni, M., Razavi Mehr, M., Abbastabar Ahangar, H., Saffar, A. (2022). Simultaneous photocatalytic degradation of cefixime and cefuroxime antibiotics using g-C3N4/NaBiO3 nanocomposite and optimization of effective parameters by response surface methodology. Reac. Kinet. Mech. Catal. 135, 1059.
[10] Jianming, X. (2009). Comparison of metronidazole degradation by different advanced oxidation processes in low concentration aqueous solutions. Chin. J. Environ. Eng. 3, 109-119.
[11] Iram, M., Guan, Y., Ishfaq, A., Liu, H. (2010). Adsorption and magnetic removal of neutral red dye from aqueous solution using Fe3O4 hollow nanospheres. J. Hazard. Mater. 181, 1039-1050.
[12] Razavi Mehr, M., Fekri, M. H., Omidali, F., Eftekhari, N., Akbari-adergani, B. (2019). Removal of Chromium (VI) from Wastewater by Palm Kernel Shell-based a Green Method. J. Chem. Health Risks. 9, 75.
[13] Fekri, M. H., Banimahd Keivani, M., Razavi Mehr, M., Akbari-adergani, B. (2019). Effective Parameters on Removal of Rhodamine B from Colored Wastewater by Nano polyaniline/Sawdust Composite. J. Mazandaran Univ. Med. Sci. 29, 166.
[14] Chegeni, M., Etemadpour, S., Fekri, M. H. (2021). The perlite-calcium alginate–activated carbon composite as an efficient adsorbent for the removal of dyes from aqueous solution. Phys. Chem. Res. 9, 1.
[15] Zare, M., Adibiyan, M., Ghasemi, E., Ashouri, F. (2022). Adsorption of Congo red dye by magnetic nanoparticles of ferrite cobalt and ferrite zinc coated with polyaniline. Journal of Applied Chemistry. 17(64), 55-70.
[16] Ali, A., Shoeb, M., Li, Y., Li, B., Khan, M. A. (2021). Enhanced photocatalytic degradation of antibiotic drug and dye pollutants by graphene-ordered mesoporous silica (SBA-15)/TiO2 nanocomposite under visible-light irradiation. J. Mol0 Liq. 324, 114696.
[17] Pandey, P., Shankar, A., Biney, M., Saini, V. K. (2021). Enhancement in amoxicillin adsorption and regeneration properties of SBA-15 after surface modification with polyaniline. Colloid and Interface Science Communications. 43, 100432.
[18] Bui, T. X., Kang, S. Y., Lee, S. H., Choi, H. (2011). Organically functionalized mesoporous SBA-15 as sorbents for removal of selected pharmaceuticals from water. J. hazard. Mater. 193, 156-163.
[19] Khanmohammadi, F., Razavi Zadeh, B. M., Azizi, S. N. (2023). Nanoparticles of SBA-15 synthesized from corn silica as an effective delivery system for valproic acid. Journal of Applied Chemistry. 17(65), 65-80.
[20] Manzano, M., Vallet-Regi, M. (2020). Mesoporous silica nanoparticles for drug delivery. Advanced functional materials.  Adv. Funct. Mater. 30, 190634.
[21] Fekri, M. H., Soleymani, S., Razavi Mehr, M., Akbari-adergani, B. (2022). Synthesis and characterization of mesoporous ZnO/SBA-16 nanocomposite: Its efficiency as drug delivery system. J. Non-Cryst. Solids. 591, 121512.
[22] Sayadi, K., Rahdar, A., Hajinezhad, M. R., Nikazar, S., Susan, M. A. (2020). Atorvastatin-loaded SBA-16 nanostructures: Synthesis, physical characterization, and biochemical alterations in hyperlipidemic rats. J. Mol. Struct. 1202, 127296.
[23] Vatanpour, V., Rabiee, H., Farahani, M. H. D., Masteri-Farahani, M., Nikakan, M. (2020). Preparation and characterization of novel nanoporous SBA-16-COOH embedded polysulfone ultrafiltration membrane for protein separation. Chemtcal Engineering Research and Design. 156, 240-250.
[24] Palos-Barba, V., Moreno-Martell, A., Hernẚndez-Morales, V., Peza-Ledesma, C. L., Rivera-Muñoz, E. M., Nava, R., Pawelec, B. (2020). SBA-16 Cage-Like Porous Material Modified with APTES as an Adsorbent for Pb2+ Ions Removal from Aqueous Solution. Materials. 13, 927.
[25] Madadi, S., Charbonneau, L., Bergeron, J. Y., Kaliaguine, S. (2020). Aerobic epoxidation of limonene using cobalt substituted mesoporous SBA-16 Part 1: Optimization via Response Surface Methodology (RSM). Appl. Catal. B. 260, 118049.
[26] Albayati, T. M., Salih, I. K., Alazzawi, H. F. (2019). Synthesis and characterization of a modified surface of SBA-15 mesoporous silica for a chloramphenicol drug delivery system. Heliyon. 5, e02539.
[27] Areawi, B. H., Mengistie, A. A. (2013). Removal of Ni (II) from aqueous solution using leaf, bark and seed of Moringa stenopetala adsorbents. Bull. Chem. Soc. Ethiop. 27, 35.