شیمى کاربردى روز

شیمى کاربردى روز

روش کارآمد نانوگاتالیزگر مغناطیسی پرلیت/اکسید آهن برای تثبیت کربن دی اکسید در شرایط بدون حلال و فشار اتمسفر

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
دانشگاه بین‌المللی امام خمینی (ره)، دانشکده علوم پایه، گروه شیمی، قزوین، ایران
چکیده
نیاز فزاینده به سوخت منجر به افزایش سطح کربن دی اکسید شده است، که باعث پیامدهای نگران کننده ای مانند تغییرات آب و هوا و گرم شدن کره زمین می شود. تثبیت کربن دی اکسید یکی از روش های حل این مشکل است. در این پژوهش از پرلیت/اکسید آهن برای تبدیل کربن دی اکسید و اپوکسیدها به کربنات های حلقوی در شرایط بدون حلال و در فشار اتمسفرکربن دی اکسید استفاده شده است. نانوکاتالیزگر مغناطیسی و فراورده های ستز شده با استفاده از روش های مختلف طیف سنجی (فروسرخ، رزونانس مغناطیسی هسته، میکروسکوپ الکترون پویشی، تجزیه وزن سنجی گرمایی و...) بررسی و شنا سایی شده است. کاتالیزگر کارایی بسیار خوبی در تولید کربنات ها از اپوکسیدها از خود نشان داد. از مزایایی این روش می توان به موارد ذیل اشاره کرد: شرایط واکنش ملایم بدون استفاده از حلال، فشار اتمسفر کربن دی اکسید، بازده بالا، روش کار ساده، کاتالیزگر ارزان و سازگار با محیط زیست، زمان واکنش کوتاه و حذف کاتالیزگر با آهن ربای خارجی. همچنین کاتالیزگر تا 5 بار (بدون کاهش قابل توجهی در کارایی) قابل استفاداست.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

An Efficient Perlite/Fe3O4 Magnetic Nanocatalyst for Carbon Dioxide Fixation Under Solvent-free Conditions at Atmospheric Pressure of CO2

نویسندگان English

Farshid Eskandari
Mohammad Bayat
Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin, Iran
چکیده English

The increasing reliance, on fuels has led to an increase in the levels of carbon dioxide causing concerning outcomes like climate change and global warming. In response to this problem, there is a solution; CO2 fixation. In this study, Fe3O4 became changed with the mineral perlite to create magnetic nanomaterials. Fe3O4/Perlite magnetic nanomaterials had been created the use of a co-precipitation technique. In this research, we have presented Perlite/Fe3O4 magnetic nanocatalyst for the transformation of carbon dioxide and epoxides into cyclic carbonates without using solvents at atmospheric pressure of CO2. The Perlite/Fe3O4 magnetic nanocatalyst and products were examined using analysis methods like FTIR, FE-SEM, VSM, EDAX, XRF, NMR, and TGA analysis. The analysis showed the success development of Fe3O4/Perlite with the favored magnetic nanoparticles on its surface. The catalyst exhibited excellent efficiency in generating cyclic carbonate through the activation of CO2 and epoxide. Among the epoxides,1-Chloro-2,3-epoxypropane completed the best conversion fee of 98%, finishing the system in a fast 4.5 h. This approach offers advantages, including mild reaction conditions, solvent-free, the atmospheric pressure of CO2, high yields, simple workup process, inexpensive catalyst, environmentally friendly, short reaction times, and convenient catalyst removal using an external magnet. The catalyst can be reused multiple times, up to 5 cycles, without a significant decrease in its efficiency.

کلیدواژه‌ها English

Perlite/Fe3O4
CO2 fixation
Magnetic nanocatalyst
Epoxide
Solvent-free
[1] Olah, G. A., Goeppert, A., & Prakash, G. S. (2009). Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons. The Journal of Organic Chemistry, 74(2), 487-498.
 [2] Trost, B. M. (2002). On inventing reactions for atom economy. Accounts of chemical research, 35(9), 695-705.
[3] Schaffner, B., Schaffner, F., Verevkin, S. P., & Borner, A. (2010). Organic carbonates as solvents in synthesis and catalysis. Chemical Reviews, 110(8), 4554-4581.
[4] Xu, K. (2004). Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chemical Reviews, 104(10), 4303-4418.
[5] Yoshida, M., & Ihara, M. (2004). Novel methodologies for the synthesis of cyclic carbonates. Chemistry–A European Journal, 10(12), 2886-2893.
 [6] Desens, W., & Werner, T. (2016). Convergent activation concept for CO2 fixation in carbonates. Advanced Synthesis & Catalysis, 358(4), 622-630.
[7] Kuruppathparambil, R. R., Robert, T. M., Pillai, R. S., Pillai, S. K. B., Shankaranarayanan, S. K. K., Kim, D., & Mathew, D. (2022). Nitrogen-rich dual linker MOF catalyst for room temperature fixation of CO2 via cyclic carbonate synthesis: DFT assisted mechanistic study. Journal of CO2 Utilization, 59, 101951.
[8] Gargiulo, N., Peluso, A., Aprea, P., Pepe, F., & Caputo, D. (2014). CO2 adsorption on polyethylenimine-functionalized SBA-15 mesoporous silica: isotherms and modeling. Journal of chemical & engineering data, 59(3), 896-902.
[9] Kulal, N., Vasista, V., & Shanbhag, G. V. (2019). Identification and tuning of active sites in selected mixed metal oxide catalysts for cyclic carbonate synthesis from epoxides and CO2. Journal of CO2 Utilization, 33, 434-444.
[10] Jung, Y., Shin, T., Kim, K., Byun, H., Cho, S. J., Kim, H., & Song, H. (2017). Rh (0)/Rh (iii) core–shell nanoparticles as heterogeneous catalysts for cyclic carbonate synthesis. Chemical Communications, 53(2), 384-387.
[11] Ema, T., Miyazaki, Y., Shimonishi, J., Maeda, C., & Hasegawa, J. Y. (2014). Bifunctional porphyrin catalysts for the synthesis of cyclic carbonates from epoxides and CO2: structural optimization and mechanistic study. Journal of the American Chemical Society, 136(43), 15270-15279.
[12] Lim, Y. A., Chong, M. N., Foo, S. C., & Ilankoon, I. M. S. K. (2021). Analysis of direct and indirect quantification methods of CO2 fixation via microalgae cultivation in photobioreactors: A critical review. Renewable and Sustainable Energy Reviews, 137, 110579.
[13] Modak, A., Ghosh, A., Mankar, A. R., Pandey, A., Selvaraj, M., Pant, K. K., & Bhaumik, A. (2021). Cross-linked porous polymers as heterogeneous organocatalysts for task-specific applications in biomass transformations, CO2 fixation, and asymmetric reactions. ACS Sustainable Chemistry & Engineering, 9(37), 12431-12460.
[14] Fu, J., Liu, K., Li, H., Hu, J., & Liu, M. (2022). Bimetallic atomic site catalysts for CO 2 reduction reactions: A review. Environmental Chemistry Letters, 1-20.
[15] Gu, Y., Ping, R., Liu, F., Zhang, G., Liu, M., & Sun, J. (2021). Novel carbon nitride/metal oxide nanocomposites as efficient and robust catalysts for coupling of CO2 and epoxides. Industrial & Engineering Chemistry Research, 60(16), 5723-5732.
[16] Rizk, H. E., Ahmed, I. M., & Metwally, S. S. (2018). Selective sorption and separation of molybdenum ion from some fission products by impregnated perlite. Chemical Engineering and Processing-Process Intensification, 124, 131-136.
[17] Erdem, T. K., Meral, Ç. A. Ğ. L. A., Tokyay, M. U. S. T. A. F. A., & Erdoğan, T. Y. (2007). Use of perlite as a pozzolanic addition in producing blended cement. Cement and Concrete Composites, 29(1), 13-21.
[18] Yilmazer, S., & Ozdeniz, M. B. (2005). The effect of moisture content on sound absorption of expanded perlite plates. Building and Environment, 40(3), 311-318.
[19] Talip, Z., Eral, M., & Hiçsönmez, Ü. (2009). Adsorption of thorium from aqueous solutions by perlite. Journal of Environmental Radioactivity, 100(2), 139-143.
[20] Hosseini, S. N., Borghei, S. M., Vossoughi, M., & Taghavinia, N. (2007). Immobilization of TiO2 on perlite granules for photocatalytic degradation of phenol. Applied Catalysis B: Environmental, 74(1-2), 53-62.
[21] Kalambate, P. K., Huang, Z., Li, Y., Shen, Y., Xie, M., Huang, Y., & Srivastava, A. K. (2019). Core@ shell nanomaterials based sensing devices: A review. TrAC Trends in Analytical Chemistry, 115, 147-161.
 [22] Keyhanian, F., Shariati, S., Faraji, M., & Hesabi, M. (2016). Magnetite nanoparticles with surface modification for removal of methyl violet from aqueous solutions. Arabian Journal of Chemistry, 9, S348-S354.
[23] Rajput, S., Pittman Jr, C. U., & Mohan, D. (2016). Magnetic magnetite (Fe3O4) nanoparticle synthesis and applications for lead (Pb2+) and chromium (Cr6+) removal from water. Journal of colloid and interface science, 468, 334-346.
 [24] Shen, L., Li, B., & Qiao, Y. (2018). Fe3O4 nanoparticles in targeted drug/gene delivery systems. Materials, 11(2), 324.
[25] Liu, M., Ye, Y., Ye, J., Gao, T., Wang, D., Chen, G., & Song, Z. (2023). Recent Advances of Magnetite (Fe3O4)-Based Magnetic Materials in Catalytic Applications. Magnetochemistry, 9(4), 110.
[26] Gawande, M. B., Monga, Y., Zboril, R., & Sharma, R. K. (2015). Silica-decorated magnetic nanocomposites for catalytic applications. Coordination Chemistry Reviews, 288, 118-143.
[27] Esmaeilpour, M., & Ghahraman Afshar, M. (2023). Magnetic Nanoadsorbent: Preparation, characterization, and Adsorption Properties for Removal of Copper(II) from Aqueous Solutions. Applied Chemistry Today, 18(69), 11-20. doi: 10.22075/chem.2023.28238.2095.
[28] Esmaeilpour, M., Ghahraman Afshar, M., & Kazemnejadi, M. (2023). Preparation, characterization, and adsorption properties of bis-salophen schiff base ligand immobilized on Fe3O4@SiO2 nanoparticles for removal of lead(II) from aqueous solutions. Applied Chemistry Today, 18(66), 125-146. doi: 10.22075/chem.2022.26312.2054
[29] Esmaeilpour, M., Larimi, A., Ghahramanafshar, M., & Faghihi, M. (2023). Ethylenediaminetetraacetic acid coated Fe₃O₄@SiO₂ nanocomposite: An effective adsorbent for the removal of copper ions from aqueous system. Applied Chemistry Today, 17(65), 45-54. doi: 10.22075/chem.2022.25323.2028
[30] Basouti, M., & Saadatjoo, N. (2017). Novel magnetic nanoparticle acid catalyst for synthesis of a facile, efficient and one-pot tri substituted imidazoles. Applied Chemistry Today, 12(45), 21-30. doi: 10.22075/chem.2017.2616
[31] nemati, F., & sabaqian, S. (2018). Nano-magnetic Fe3O4@cellulose-NH2-CuI composite: A simple, effective and reusable heterogeneous catalyst for N-arylation of amines and nitrogen heterocycles. Applied Chemistry Today, 13(47), 119-130. doi: 10.22075/chem.2018.2866
[32] Brindha, K., Amutha, P., Krishnakumar, B., & do Nascimento Sobral, A. J. F. (2019). BiCl3-modified perlite as an effective catalyst for selective organic transformations: a green protocol. Research on Chemical Intermediates, 45, 4367-4381.
[33] KUTLUAY, S., ŞAHİN, Ö., & ECE, M. Ş. (2021). Fabrication and Detailed Characterization of Perlite Mineral Supported a New Magnetic Nanomaterial.
[34] Ahmed, I. M., Hamed, M. M., & Metwally, S. S. (2020). Experimental and mathematical modeling of Cr (VI) removal using nano-magnetic Fe3O4-coated perlite from the liquid phase. Chinese Journal of Chemical Engineering, 28(6), 1582-1590.
[35] Aksoy, Ö., Alyamaç, E., Mocan, M., Sütçü, M., Özveren-Uçar, N., & Özgür Seydibeyoğlu, M. (2022). Characterization of perlite powders from Izmir, Türkiye region. Physicochemical Problems of Mineral Processing, 58(6).
[36] Kolvari, E., Koukabi, N., & Hosseini, M. M. (2015). Perlite: A cheap natural support for the immobilization of sulfonic acid as a heterogeneous solid acid catalyst for the heterocyclic multicomponent reaction. Journal of Molecular Catalysis A: Chemical, 397, 68-75.
[37] Ece, M. S., Kutluay, S., Şahin, O., & Horoz, S. (2020). Development of novel Fe3O4/AC@ SiO2@ 1, 4-DAAQ magnetic nanoparticles with outstanding VOC removal capacity: characterization, optimization, reusability, kinetics, and equilibrium studies. Industrial & Engineering Chemistry Research, 59(48), 21106-21123.
[38] Ok, R. A., & Kutluay, S. (2023). Designing novel perlite-Fe3O4@ SiO2@ 8-HQ-5-SA as a promising magnetic nanoadsorbent for competitive adsorption of multicomponent VOCs. Chemosphere338, 139636.
 [39] Bezaatpour, A., Amiri, M., Vocke, H., Bottke, P., Zastrau, M. F., Weers, M., & Wark, M. (2023). Low-pressure CO2 fixation with epoxides via a new modified nanocrystalline NH2-MIL-101 (Cr) in Solvent-free and cocatalyst-free conditions. Journal of CO2 Utilization, 68, 102366.
[40] Jahanshahi, R., & Akhlaghinia, B. (2015). Expanded perlite: an inexpensive natural efficient heterogeneous catalyst for the green and highly accelerated solvent-free synthesis of 5-substituted-1 H-tetrazoles using [bmim] N 3 and nitriles. RSC advances5(126), 104087-104094.
 
[41] Yan, T., Liu, H., Zeng, Z. X., & Pan, W. G. (2023). Recent progress of catalysts for synthesis of cyclic carbonates from CO2 and epoxides. Journal of CO2 Utilization68, 102355.
[42] Liu, X., Zhang, S., Song, Q. W., Liu, X. F., Ma, R., & He, L. N. (2016). Cooperative calcium-based catalysis with 1, 8-diazabicyclo [5.4. 0]-undec-7-ene for the cycloaddition of epoxides with CO2 at atmospheric pressure. Green Chemistry, 18(9), 2871-2876.
[43] Nazeri, M. T., Ramezani, M., Javanbakht, S., & Shaabani, A. (2022). Chemical CO2 fixation using a green biocatalytic system based on Ugi conjugated cobalt phthalocyanine on cellulose. Sustainable Energy & Fuels, 6(22), 5134-5145
[44] Mamone, M., Milcent, T., & Crousse, B. (2015). Reactivity of carbon dioxide in hydrofluoroethers: a facile access to cyclic carbonates. Chemical Communications, 51(64), 12736-12739.
[45] Lu, X. B., Wang, H., & He, R. (2002). Aluminum phthalocyanine complex covalently bonded to MCM-41 silica as heterogeneous catalyst for the synthesis of cyclic carbonates. Journal of Molecular Catalysis A: Chemical186(1-2), 33-42.
[46] Maksimchuk, N. V., Ivanchikova, I. D., Ayupov, A. B., & Kholdeeva, O. A. (2016). One-step solvent-free synthesis of cyclic carbonates by oxidative carboxylation of styrenes over a recyclable Ti-containing catalyst. AppliedCatalysisB:Environmental181, 363-370.
[47] Srivastava, R., Srinivas, D., & Ratnasamy, P. (2006). Sites for CO2 activation over amine-functionalized mesoporous Ti (Al)-SBA-15 catalysts. Microporous and Mesoporous Materials90(1-3), 314-326.
[48] Liu, D., Li, G., Liu, J., & Yi, Y. (2019). Organic-inorganic hybrid mesoporous titanium silica material as bi-functional heterogeneous catalyst for the CO2 cycloaddition. Fuel244, 196-206.