سنتز و بررسی خصوصیات اکسید گرافن کاهیده اصلاح شده با استفاده از ال- لیزین و مس برای واکنش‌های تولید اکسیژن و هیدروژن

نوع مقاله : مقاله علمی پژوهشی

نویسندگان

1 دانشکده شیمی، دانشکدگان علوم، دانشگاه تهران، تهران، ایران

2 دانشکده شیمی، پردیس البرز، دانشگاه تهران، تهران، ایران

چکیده

در این پژوهش، فعالیت الکتروکاتالیستی اکسید گرافن (GO) عامل‌دار شده با استفاده از اسیدآمینه ال- لیزین (GO-Lys) و همچنین ال- لیزین و مس (GO-Lys-Cu) برای واکنش‌های تولید اکسیژن و هیدروژن مورد ارزیابی قرار گرفت. شناسایی و مشخصه‌یابی نمونه‌های GO، GO-Lys و GO-Lys-Cu با استفاده از فناوری‌های پراش پرتو ایکس، طیف‌بینی مادون قرمز تبدیل فوریه، طیف‌بینی رامان، میکروسکوپ الکترونی روبشی گسیل میدانی و تصاویر نقشه‌برداری عنصری انجام شد. همچنین به منظور بررسی خواص الکتروشیمیایی و فعالیت‌های الکتروکاتالیستی نمونه‌ها از طیف سنجی امپدانس الکتروشیمیایی (EIS) و ولتامتری روبش خطی (LSV) استفاده شد. نتایج بدست آمده نه تنها تزئین سطح اکسید گرافن توسط Lys و Lys-Cu را تایید کرده است، بلکه همچنین کاهش صفحات اکسید گرافن و تبدیل آن به اکسید گرافن کاهیده (rGO) را نشان داده است. از طرف دیگر، نتیجه-های EIS کمترین مقاومت انتقال بار برای نانوکامپوزیت هیبریدی Lys-rGO در مقایسه با سایر نمونه‌ها را تایید کرده است. نتیجه‌های بدست آمده از LSV نشان می‌دهد که عامل‌دار کردن GO با گروه عاملی آمین Lys-Cu منجر به فعالیت الکتروکاتالیستی کارآمد و پایدار برای واکنش تولید اکسیژن (OER) و واکنش تولید هیدروژن (HER) با کمترین پتانسیل مازاد (mV 375 و 732، به ترتیب) در چگالی جریان mA/cm2 10 در محیط قلیایی و کوچک‌ترین شیب تافل mV/dec ٣٤٦ و 160، به ترتیب برای OER و HER، در مقایسه با نمونه‌های GO، L-Lys، GO-Lys و Lys-Cu شده است.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Synthesis and Investigation of Properties of Reduced Graphene Oxide Modified Using L-lysine and Copper for Oxygen and Hydrogen Evolution Reactions

نویسندگان [English]

  • Fatemeh Rahnemaye Rahsepar 1
  • Sirwan Muhammed Al-Dalawi 2
  • Mustafa Farajzadeh 1
1 School of Chemistry, College of Science, University of Tehran, Tehran 1417614411, Iran
2 Department of Chemistry, Alborz Campus University of Tehran, Tehran, Iran
چکیده [English]

In this study, the electrocatalytic activity of the functionalized graphene oxide (GO) using L-lysine (GO-Lys) as well as L-lysine and copper (GO-Lys-Cu) was investigated for oxygen and hydrogen evolution reactions. Identification and characterization of GO, GO-Lys and GO-Lys-Cu were done using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, field emission scanning electron microscopy (FESEM) and elemental mapping images. Also, electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV) were used to investigate the electrochemical properties and electrocatalytic activities. The obtained results not only confirmed the decoration of the GO surface by Lys and Lys-Cu, but also revealed the reduction of graphene oxide (rGO) sheets. EIS results confirmed the lowest charge transfer resistance for Lys-rGO hybrid nanocomposite compared to other synthesized samples. The results obtained of LSV show that the functionalization of GO with Lys-Cu leads to efficient and stable electrocatalytic activity for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) with the lowest overpotential (375 and 732 mV, respectively) at the current density of 10 mA/cm2 (1 M KOH) and the smallest Tafel slope is 346 and 160 mV/dec, respectively, compared to GO, L-Lys, GO-Lys and Lys-Cu samples.

کلیدواژه‌ها [English]

  • Electrocatalyst
  • L-lysine
  • Graphene oxide nanocomposite
  • Hydrogen evolution reaction
  • Oxygen evolution reaction
[1] Ma, Y., Dai, X., Liu, M., Yong, J., Qiao, H., Jin, A., Li, Z., Huang, X., Wang, H., & Zhang, X. (2016). Strongly Coupled FeNi Alloys/NiFe2O4@Carbonitride Layers-Assembled Microboxes for Enhanced Oxygen Evolution Reaction. ACS Applied Materials and Interfaces, 8 (50), 34396–34404.
[2] Bruce, P.G., Freunberger, S.A., Hardwick, L.J., & Tarascon, J.M. (2012). Erratum: Li-O2 and Li-S batteries with high energy storage. Nature Materials, 11 (172), 19-29.
[3] Lewis, N.S., & Nocera, D.G. (2006). Powering the planet: Chemical challenges in solar energy utilization. The Proceedings of the National Academy of Sciences, 103 (43), 15729–15735.
[4] Yan, J., Savenije, T.J., Mazzarella, L., & Isabella, O. (2022). Progress and challenges on scaling up of perovskite solar cell technology. Sustainable Energy Fuels, 6 (2), 243–266.
[5] Aricò, A.S., Bruce, P., Scrosati, B., Tarascon, J.-M., & van Schalkwijk, W. (2005). Nanostructured materials for advanced energy conversion and storage devices. Nature Materials, 4 (5), 366–377.
[6] Jafari Foruzin, L., Rezvani, Z., & Nejati, K. (2021). Preparation of Ni-Fe-layered double hydroxide with high surface area as electrocatalyst for water oxidation in neutral media. Applied Chemistry, 17(64), 45-54. (in persion)
[7] Guo, W., Sun, W., Lv, L.-P., Kong, S,. & Wang, Y. (2017). Microwave-Assisted Morphology Evolution of Fe-Based Metal–Organic Frameworks and Their Derived Fe2O3 Nanostructures for Li-Ion Storage. ACS Nano, 11 (4), 4198–4205.
[8] Seh, Z.W., Kibsgaard, J., Dickens, C.F., Chorkendorff, I., Nørskov, J.K., & Jaramillo, T.F. (2017). Combining theory and experiment in electrocatalysis: Insights into materials design. Science, 355 (6321), 4998.
[9] Zhang, F.S., Wang, J.W., Luo, J. Liu, R.R., Zhang, Z.M., He, C.T., & Lu, T.B. (2018). Extraction of nickel from NiFe-LDH into Ni2P@NiFe hydroxide as a bifunctional electrocatalyst for efficient overall water splitting. Chemical Science, 9 (5), 1375–1384.
[10] Amirhosseiny, A., & Zarei, K. (2019). Electrochemical preparation of an electrocatalytical layer containing hollow platinum nanoparticles and reduced graphene oxide on the pencil graphite electrode for hydrogen evolving reaction. Applied Chemistry, 14(51), 135-146. (in persion)
[11] Nozari-asbmarz, M., Amiri, M., Bezaatpour, A., & Arshi, S. (2020). The effect of nickel salt source and anion of electrolyte on electro-driven water oxidation activity using nickel hydroxide thin film. Applied Chemistry, 16(58), 137-148. (in persion)
[12] Ghaffarinead, A., Tabatabaei, A., Sohrabi, B., & Salahandish, R. (2019). The effect of surfactants on electrochemical hydrogen production. Applied Chemistry, 14(50), 25-40. (in persion)
[13] Mozafari, S. A., Bahmai, M., Mahdian, M., & Rahmanian, R. (2017). Electrochemical preparation of electrocatalytic layer of platinum nanoparticles of polymer fuel cell electrode and evaluation of its electrocatalytic activity in oxygen reduction reaction. Applied Chemistry, 10(34), 91-108. (in persion)
[14] Halder, A., Zhang, M., & Chi, Q. (2016). Advanced Catalytic Materials - Photocatalysis and Other Current Trends (Chapter 14). IntechOpen.
[15] Bhowmick, S., Alam, S., Shah, A.K., & Qureshi, M. (2021). Bimetallic cyclic redox couple in dimanganese copper oxide supported by nickel borate for boosted alkaline electrocatalytic oxygen evolution reaction. Sustain. Energy & Fuels, 5 (9), 2517–2527.
[16] Roy, A., Jadhav, H.S., Cho, M., & Seo, J.G. (2019). Electrochemical deposition of self-supported bifunctional copper oxide electrocatalyst for methanol oxidation and oxygen evolution reaction. Journal of Industrial and Engineering Chemistry, 76, 515–523.
[17] Feng, Y. Y., Si, S., Deng, G., Xu, Z. X., Pu, Z., Hu, H. S., & Wang, C. B. (2022). Copper-doped ruthenium oxide as highly efficient electrocatalysts for the evolution of oxygen in acidic media. Journal of Alloys and Compounds, 892, 162113.
[18] Inamuddin, Boddula, R. & Asiri, A.M. (2020). Methods for Electrocatalysis: Advanced Materials and Allied Applications (Vol. 6). Springer Cham.
[19] Priyadarsini, S., Mohanty, S., Mukherjee, S., Basu, S., & Mishra, M. (2018). Graphene and graphene oxide as nanomaterials for medicine and biology application. Journal of Nanostructure in Chemistry, 8(2), 123–137.
[20] Mousavi, S.M., Hashemi, S.A., Ghasemi, Y., Amani, A.M., Babapoor, A., & Arjmand, O. (2019). Applications of graphene oxide in case of nanomedicines and nanocarriers for biomolecules: review study. Drug Metabolism Reviews, 51(1), 12–41.
[21] Rathinam, N.K., Salem, D.R., & Sani, R.K. (2018). Microbial Electrochemical Technology: Biofilm Engineering for Improving the Performance of Microbial Electrochemical Technologies (Chapter 2.4). Elsevier.
[22] Tiwari, S.K., Sahoo, S., Wang, N., & Huczko, A. (2020). Graphene research and their outputs: Status and prospect. Journal of Science: Advanced Materials and Devices, 5(1), 10–29.
[23] Madhariya, G., Diwan, S., Chauhan, R., Chandrawanshi, N. K., & Mahish, P. K. (2023). Handbook of Biomolecules: Current applications of biomolecules in biotechnology (Chapter 20). Elsevier.
[24] Datta, L.P., Manchineella, S., & Govindaraju, T. (2020). Biomolecules-derived biomaterials. Biomaterials, 230, 119633.
[25] Sapner, V.S., Chavan, P.P., & Sathe, B.R. (2020). L -Lysine-Functionalized Reduced Graphene Oxide as a Highly Efficient Electrocatalyst for Enhanced Oxygen Evolution Reaction. ACS Sustainable Chemistry & Engineering, 8(14), 5524–5533.
[26] Sapner, V.S., Chavan, P.P., Munde, A. V., Sayyad, U.S., & Sathe, B.R. (2021). Heteroatom (N, O, and S)-Based Biomolecule-Functionalized Graphene Oxide: A Bifunctional Electrocatalyst for Enhancing Hydrazine Oxidation and Oxygen Reduction Reactions. Energy and Fuels, 35(8), 6823–6834.
[27] Hummers, W.S., & Offeman, R.E. (1958). Preparation of Graphitic Oxide. Journal of the American Chemical Society, 80(6), 1339-1339.
[28] Abdelhalim, A.O.E., Sharoyko, V. V., Meshcheriakov, A.A., Martynova, S.D., Ageev, S. V. Iurev, G.O., Al Mulla, H., Petrov, A. V., Solovtsova, I.L., Vasina, L. V., Murin, I. V., & Semenov, K.N. (2020). Reduction and functionalization of graphene oxide with L-cysteine: Synthesis, characterization and biocompatibility. Nanomedicine: Nanotechnology, Biology and Medicine, 29,102284.
[29] Mo, Z., Gou, H., He, J., Yang, P., Feng, C., & Guo, R. (2012). Controllable synthesis of functional nanocomposites: Covalently functionalize graphene sheets with biocompatible L-lysine. Applied Surface Science, 258(22), 8623–8628.
[30] Guo, Z., Huang, G.Q., Li, J., Wang, Z.Y., & Xu, X.F. (2015) Graphene oxide-Ag/poly-l-lysine modified glassy carbon electrode as an electrochemical sensor for the determination of dopamine in the presence of ascorbic acid. Journal of Electroanalytical Chemistry, 759(2), 113–121.
[31] Guo, W., Zhao, B., Zhou, Q., He, Y., Wang, Z., & Radacsi, N. (2019). Fe-Doped ZnO/Reduced Graphene Oxide Nanocomposite with Synergic Enhanced Gas Sensing Performance for the Effective Detection of Formaldehyde. ACS Omega, 4(6), 10252-10262.
[32] Mahmoud, N.E., & Abdelhameed, R.M. (2021). Plant Stress Superiority of modified graphene oxide for enhancing the growth , yield , and antioxidant potential of pearl millet ( Pennisetum glaucum L.) under salt stress. Plant Stress, 2, 100025.
[33] Soomro, S.A., Gul, I.H., Naseer, H., Marwat, S., & Mujahid, M. (2018). Improved Performance of CuFe2O4/rGO Nanohybrid as an Anode Material for Lithium-ion Batteries Prepared Via Facile One-step Method. Current Nanoscience, 15(4), 420-429.
[34] Wu, Z., Fu, Z., Tian, Y., Hasan, M., Huang, L., Yang, Y., Li, C., Zafar, A., & Shu, X. (2022). Fabrication and characterization of lysine hydrochloride Cu (II) complexes and their potential for bombing bacterial resistance. Green Processing and Synthesis, 11 (1), 445–457.
[35] Zhou, X., Huang, H., Zhu, R., Sheng, X., Xie, D., & Mei, Y. (2019). Progress in Organic Coatings Facile modi fi cation of graphene oxide with Lysine for improving anti-corrosion performances of water-borne epoxy coatings. Progress in Organic Coatings, 136, 105200.
[36] Prakash, V., Sharma, S., Kaur, J., & Mehta, S.K. (2018). Graphene oxide/lysine composite-a potent electron mediator for detection of diazepam. Analytical Methods, 10(41), 5038–5046.
[37] Homayoun, A., Hamed, K., & Hojat, V. (2016). Green synthesis and characterization of spherical copper nanoparticles as organometallic antibacterial agent. Applied Organometallic Chemistry, 31(7), e3642.
[38] Phul, R., Kaur, C., Farooq, U., & Ahmad, T. (2018). Ascorbic acid assisted synthesis , characterization and catalytic application of copper nanoparticles. Material Science & Engineering International Journal, 2(4), 90-94.
[39] Hossain, O., Ahmed, S., Rahman, E., Roy, H., & Azam, S. (2021). Synthesis, characterization, and comparative assessment of antimicrobial properties and cytotoxicity of graphene-, silver-, and zinc-based nanomaterials. Analytical Science Advances, 3(1-2), 54–63.
[40] Chireh, M., Naseri, M., & Ghiasvand, S. (2019). Enhanced photocatalytic and antibacterial activities of RGO/LiFe5O8 nanocomposites. Journal of Photochemistry and Photobiology A: Chemistry, 385, 112063.
[41] Gupta, A., Jamatia, R., Patil, R.A., Ma, Y., & Pal, A.K. (2018). Copper Oxide / Reduced Graphene Oxide Nanocomposite-Catalyzed Synthesis of Flavanones and Flavanones with Triazole Hybrid Molecules in One Pot : A Green and Sustainable Approach, ACS Omega, 3(7), 7288–7299.
[42] Yan, Y., Li, C., Wu, H., Du, J., Feng, J., Zhang, J., Huang, L., Tan, S., & Shi, Q. (2019). Montmorillonite-modified reduced graphene oxide stabilizes copper nanoparticles and enhances bacterial adsorption and antibacterial activity. ACS Applied Bio Materials, 2(5), 1842-1849.
[43] Ye, X., Feng, J., Zhang, J., Yang, X., Liao, X., Shi, Q., & Tan, S. (2016). Controlled Release and Long-Term Antibacterial Activity of Reduced Graphene Oxide/Quaternary Ammonium Salt Nanocomposites Prepared by Non-covalent Modification, Colloids and Surfaces B: Biointerface, 149, 322-329.
[44] Ngouoko, J.J.K., Tajeu, K.Y., Temgoua, R.C.T., Doungmo, G., Doench, I., Tamo, A.K., Kamgaing, T., Osorio-Madrazo, A., & Tonle, I.K. (2022). Hydroxyapatite/L-Lysine Composite Coating as Glassy Carbon Electrode Modifier for the Analysis and Detection of Nile Blue A. Materials, 15(12), 4262.
[45] Mali, K. S., Greenwood, J., Adisoejoso, J., Phillipson, R., & De Feyter, S. (2015). Nanostructuring graphene for controlled and reproducible functionalization. Nanoscale, 7(5), 1566-1585.
[46] Xu,Y., Shi, Y., Lei, F., & Dai, L. (2019). A novel and green cellulose-based Schiff base-Cu (II) complex and its excellent antibacterial activity. Carbohydrate Polymers, 230, 115671.
[47] Dar, M.A., Nam, S.H., Kim, Y., & Kim, W. (2010). Synthesis, characterization, and electrochemical properties of self-assembled leaf-like CuO nanostructures. Journal of Solid State Electrochemistry, 14(9), 1719-1726.
[48] Singh, P., Nath, P., Arun, R. K., Mandal, S., & Chanda, N. (2016). Novel synthesis of a mixed Cu/CuO–reduced graphene oxide nanocomposite with enhanced peroxidase-like catalytic activity for easy detection of glutathione in solution and using a paper strip. The Royal Society of Chemistry, 6(95), 92729-92738.
[49] Xiao, Y., Li, X., Zai, J., Wang, K., Gong, Y. Li, B., Han, Q., & Qian, X. (2014). CoFe2O4-Graphene Nanocomposites Synthesized through An Ultrasonic Method with Enhanced Performances as Anode Materials for Li-ion Batteries. Nano-Micro Letters, 6(4), 307–315.
[50] Wu, F., Liang, J., & Li, W. (2015). Electrochemical deposition of Mg(OH)2/GO composite films for corrosion protection of magnesium alloys. Journal of Magnesium and Alloys, 3(3), 231–236.
[51] Akbari, E., Akbari, I., & Ebrahimi, M.R. (2019). sp2/sp3 bonding ratio dependence of the band-gap in graphene oxide. The European Physical Journal B, 92(4), 71.
[52] Hidayah, N. M. S., Liu, W.-W., Lai, C.-W., Noriman, N. Z., and Khe, C.-S., Hashim, U., & Lee, H. (2017).
Comparison on Graphite , Graphene Oxide and Reduced Graphene Oxide : Synthesis and Characterization. AIP Conference Proceedings, 1892(1), 150002.
[53] Wang, S., Lu, A., & Zhong, C. J. (2021). Hydrogen production from water electrolysis: role of catalysts. Nano Convergence, 8(1), 4.
[54] Paul, A. M., Sajeev, A., Nivetha, R., Gothandapani, K., Bhardwaj, P., Govardhan, K., Raghavan, V., Jacob, G., Sellapan, R., Jeong, S. K., & Grace, A. N. (2020). Cuprous oxide (Cu2O)/graphitic carbon nitride (g-C3N4) nanocomposites for electrocatalytic hydrogen evolution reaction. Diamond and Related Materials, 107(1), 107899.
[55] Ahmad, A., Davarpanah, A., Thangavelu, L., Bokov, D. O., Alshgari, R. A., & Karami, A. M. (2022). Self-assembled pine-like CuCo/CP configuration as efficient electrocatalysts toward electrochemical water splitting. Journal of Molecular Liquids, 351(1), 118635.
[56] Wu, H., Zhai, Q., Ding, F., Sun, D., Ma, Y., Ren, Y., Wang, B., Li, F., Bian, H., Yang, Y., Chen, L., Tang, S., & Meng, X. (2022). Amorphous FeNiCu-MOF as highly efficient electrocatalysts for oxygen evolution reaction in alkaline medium. Dalton Transactions, 51(37), 14306.
[57] Ren, X., Ji, X., Wei, Y., Wu, D., Zhang, Y., Ma, M., Liu, Z., Asiri, A. M., Wei, Q., & Sun, X. (2018). In situ electrochemical development of copper oxide nanocatalysts within a TCNQ nanowire array: A highly conductive electrocatalyst for the oxygen evolution reaction. Chemical Communications, 54(12), 1425.