شیمى کاربردى روز

شیمى کاربردى روز

سنتز سبز و آسان نانوکامپوزیت گرافن اکسید کاهش یافته-نقره به عنوان یک فتوکاتالیزور پلاسمونیک نور مرئی

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
شیمی معدنی، دانشکده شیمی، دانشگاه صنعتی شاهرود، شاهرود، ایران
چکیده
در این پژوهش، نانوکامپوزیت گرافن اکسید کاهش یافته-نقره (Ag-RGO) به روش سبز و آسان سنتز شد. در این مسیر، از عصاره عناب در نقش کاهنده و پایدار کننده نانوکامپوزیت در یک محیط آبی بدون کاهنده شیمیایی و پیچیدگی خاص استفاده شد. گرافن اکسید کاهش یافته به عنوان یک پشتیبان به دلیل مساحت سطح بالا و پایداری شیمیایی و رسانایی خوب استفاده گردید. این نانوکامپوزیت Ag-RGO به وسیله روش های متداول نظیر طیف سنجی فروسرخ تبدیل فوریه (FT-IR)، الگوی پراش پرتو X (XRD)، میکروسکوپ الکترونی روبشی (FE-SEM)، طیف سنجی پراش انرژی پرتو ایکس (EDS)، طیف سنجی مرئی- ماوراء بنفش (UV-Vis) و طیف سنجی رامان (Raman) شناسایی شد. نانوکامپوزیت Ag-RGO به عنوان یک فتوکاتالیزور پلاسمونیک نور مرئی در تخریب رنگ رودآمین بی در محلول آبی بکار گرفته شد. همچنین عوامل موثر بر تخریب فتوکاتالیزوری نظیر غلظت رنگ رودآمین بی، مقدار نانوکامپوزیت Ag-RGO و pH اولیه محلول، مورد بررسی قرار گرفت. نتایج نشان داد که میزان تخریب 100/0 میلی‌لیتر محلول رودآمین بی ppm 1، به وسیله 0/020 گرم نانوکامپوزیت Ag-RGO در pH مساوی 6، طی 45 دقیقه تحت تابش نور مرئی برابر با 91/34 درصد بود. همچنین مشخص شد که سرعت تخریب رنگ از سینیتیک شبه مرتبه اول تبعیت می‌کند.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Green and Facile Synthesis of Reduced Graphene Oxide-Silver Nanocomposite as a Visible Light Plasmonic Photocatalyst

نویسندگان English

Esmat Mohammadi
Esmaiel Soleimani
Inorganic Chemistry Research Laboratory, Faculty of Chemistry, Shahrood University of Technology, Shahrood, Iran
چکیده English

In this research, reduced graphene oxide-silver nanocomposites (RGO-Ag NCs) was synthesized by a green and easy method. In this direction, jujube extract was used as a reducing and stabilizer of nanocomposites in an aqueous environment without chemical reducing and special complexity. Reduced graphene oxide was used as a support because of its high surface area, chemical stability, and good conductivity. This RGO-Ag NCs is characterized by conventional methods such as Fourier Transform Infrared Spectroscopy (FT-IR), X-ray Diffraction Pattern (XRD), Scanning Electron Microscope (FE-SEM), X-ray Energy Diffraction Spectroscopy (EDS), Visible-Ultraviolet spectroscopy (UV-Vis) and Raman spectroscopy. The RGO-Ag NCs was used as a visible light plasmonic photocatalyst in the degradation of Rhodamine B dye in aqueous solution. Also, factors affecting photocatalytic degradation such as Rhodamine B dye concentration, amount of RGO-Ag NCs and initial pH of the solution were investigated. The results showed that the degradation rate of 100.0 mL of 1 ppm rhodamine B solution by 0.020 g of RGO-Ag NCs at pH = 6 within 45 minutes under visible light irradiation was 91.34%. It was also found that the rate of dye degradation follows pseudo-first-order.

کلیدواژه‌ها English

Jujube extract
reduced graphene oxide-silver
photocatalytic degradation of rhodamine B
plasmonic photocatalyst
[1] Behravan, M., Panahi, A. H., Naghizadeh, A., Ziaee, M., Mahdavi, R., & Mirzapour, A. (2019). Facile green synthesis of silver nanoparticles using Berberis vulgaris leaf and root aqueous extract and its antibacterial activity. International Journal of Biological Macromolecules,124, 148-154.
[2] Karimi, M. J., Mahdian, S. A., & Babaeizadeh, V. (2017). Synthesis of Ag nanoparticles by Urtica extract and investigation of its of its effect on electron transfer resistant in conductive systems. Journal of Applied Chemistry, 12(44), 161-170 (in Persian).
[3] Faraji, M., Derakhshi, P., & Tahvildari, K. (2018). Green and facile synthesis of graphene supported Pt nanoparticles for oxygen reduction reaction in polymer electrolyte fuel cells. Journal of Applied Chemistry, 12(45), 31-39.
[4] Kakaei, K., & Ghadimi, G. (2019). Synthesis of silver nanoparticles based on reduced graphene oxide as an electrocatalyst for cathod side of fuel cells. Journal of Applied Chemistry, 14(52), 25-30 (in Persian).
[5] Iravani, S. (2011). Green synthesis of metal nanoparticles using plants. Green Chemistry, 13(10), 2638-2650.
[6] Kulkarni, N., & Muddapur, U. (2014). Biosynthesis of metal nanoparticles: A review. Journal of Nanotechnology, 2014, 510246.
[7] Hossain, M.A. (2018). A phytopharmacological review on the Omani medicinal plant: Ziziphus jujube. Journal of King Saud University, 31(4), 1352-1357.
[8] Ji, X., Peng, Q., Yuan, Y., Shen, J., Xie, X., & Wang, M. (2017). Isolation, structures and bioactivities of the polysaccharides from jujube fruit (Ziziphus jujuba Mill.): A review. Food Chemistry, 227, 349-357.
[9] Gao, Q. H., Wu, C. S., & Wang, M. (2013). The jujube (Ziziphus jujuba Mill.) fruit: A review of current knowledge of fruit composition and health benefits. Journal of Agricultural and Food Chemistry, 61(14), 3351-3363.
[10] Elliott, G. S., Mason, R. W., & Edwards, I. R. (1990). Studies on the pharmacokinetics and mutagenic potential of Rhodamine B. Journal of Toxicology.: Clinical Toxicology, 28(1), 45-59.
[11] Agorku, E. S., Mamo, M. A., Mamba, B. B., Pandey, A. C., & Mishra, A. K. (2015). Palladium-decorated zinc sulfide/reduced graphene oxide nanocomposites for enhanced visible light-driven photodegradation of Indigo carmine. Material Science in Semiconductor Processing, 33, 119-126.

[12] AreebA., Yousaf, T., Murtaza, M.ZahraM., Zafar, M. I. & Waseem, A. (2021) Green photocatalyst Cu/NiO doped zirconia for the removal of environmental pollutants. Material Today Communication, 28, 102678.

[13] Abdul-Kader, H. D., MohammedI. Sh., Ammar, S.H.  (2020). Synthesis of recycle-able core/shell CoFe2O4@CoWO4 photocatalysts for efficient visible-light photo-catalytic degradation of environmental pollutants. Environmental Nanotechnology, Monitoring & Management, 17, 100664.

[14] Zhao, Y.Wang, Y., Xiao, G.& Su, H. (2019). Fabrication of biomaterial/ TiO2 composite photocatalysts for the selective removal of trace environmental pollutants. Chinese Journal of Chemical Engineering, 27(26), 1416-1428.

[15] Balakumar, S., Mahesh, N., Kamaraj, M., Shyamalagowri, S., Manjunathan, J., Murugesan, S., Aravind, J., & Babu, P. S. (2020). Outlook on bismuth-based photocatalysts for environmental applications: A specific emphasis on Z-scheme mechanisms. Chemosphere, 303(Part 1), 135052.

[16] Mohd-RazaliN. A.Wan-Salleh, W. N.Aziz, F., Jye, L. W., Yusof, N.& Ismail, A.F. (2021). Review on tungsten trioxide as a photocatalysts for degradation of recalcitrant pollutants. Journal of Cleaner Production, 309, 127438.

[17] Ali, S., Abdul-Nasir, J., Dara, R.N., & Rehman, Z. (2022). Modification strategies of metal oxide photocatalysts for clean energy and environmental applications: A review. Inorganic Chemistry Communications, 145, 110011.

[18] Fauzi, A. A., Jalil, A. A., Hassan, N. S., Aziz, F. F. A., Azami, M. S., Hussain, I., Saravanan, R., & Vo, D.-V. V. (2020). A critical review on relationship of CeO2-based photocatalyst towards mechanistic degradation of organic pollutant. Chemosphere, 286(Part 1), 131651.

[19] GuptaP., & Rathore, V. (2021). Study of TiO2 material: A photocatalyst for contrary pollutants. Materials Today Proceedings, 42(Part 2), 1345-1352.

[20] Meng, L., Qu, Y.,  & Jing, L. (2021). Recent advances in BiOBr-based photocatalysts for environmental remediation. Chinese Chemical Letter, 32(11), 3265-3276.

[21] Augustynski, J.Bienkowski, K.& Solarska, R. (2016). Plasmon resonance-enhanced photoelectrodes and photocatalysts. Coordination Chemistry Review, 325, 116-124.

[22] Gellé, A.& Moores, A. (2019). Plasmonic nanoparticles: Photocatalysts with a bright future. Current Opinion in Green and Sustainable Chemistry, 15, 60-66.

[23] Ma, Y., Zhu, X., Xu, S., He, G., Yao, L.Hu, N.Su, Y., Feng, J., ZhangY.& Yang, Z. (2018).  Gold nanobipyramid@cuprous oxide jujube-like nanostructures for plasmon enhanced photocatalytic performance. Applied Catalysis B: Environmental, 234, 26-36.

[24] Li, Y. Liao, D.,  Li, T.,  Zhong, W.,  Wang, X. Hong, X. Yu, H. (2020). Plasmonic Z-scheme Pt-Au/ BiVO4 photocatalyst: Synergistic effect of crystal-facet engineering and selective loading of Pt-Au cocatalyst for improved photocatalytic performance. Journal of Colloid and Interface Science, 570, 232-241.

[25] Meng, X.& Zhang, Z. (2017). Pd-doped Bi2MoO6 plasmonic photocatalysts with enhanced visible light photocatalytic performance. Applied Surface Science, 392, 169-180.

[26] Awazu, K., Fujimaki, M., Rockstuhl, C., Tominaga, J., Murakami, H., Ohki, Y., Yoshida, N., & Watanabe, T. (2008). A plasmonic photocatalyst consisting of silver nanoparticles embedded in titanium dioxide. Journal of the American Chemical Society, 130(5), 1676-1680.
[27] Li, C., Wang, B., Zhang, F., Song, N., Liu, G., Wang, C., & Zhong, S. (2020). Performance of Ag/BiOBr/GO composite photocatalyst for visible-light-driven dye pollutants degradation. Journal of Materials Research and Technology, 9(1), 610–621.
[28] Ouyang, K., Yang, C., Xu, B., Wang, H., & Xie, S. (2021). Synthesis of novel ternary Ag/BiVO4/GO photocatalyst for degradation of oxytetracycline hydrochloride under visible light. Colloids Surfaces A: Physicochemical and Engineering Aspects, 625, 126978.
[29] Abolhasani, J., Samadi, A., Ghorbani-Kalhor, E., & Serrpoush-Hamid, N. (2014). Colorimetric determination of thioamide drugs based on the surface plasmon resonance band of colloidal silver nanoparticles. Journal of Applied Chemistry, 8(29), 25-30.
[30] Sotoodeh, E., Almasifar, D., Burromand-Piroze, J. (2021). Measuring of metanephrine by UV-Vis peak of surface absorption Plasmon resonance of silver nanoparticles by response surface methodology. Journal of Applied Chemistry, 12(44), 161-170 (in Persian).
[31] Gang, R., Xia, Y., Xu, L., Zhang, L., Ju, S., Wang, Z., & Koppala, S. (2022). Size controlled Ag decorated TiO2 plasmonic photocatalysts for tetracycline degradation under visible light. Surfaces and Interfaces, 31, 102018.
[32] Bora, T., & Dutta, J. (2019). Plasmonic photocatalyst design: Metal–semiconductor junction affecting photocatalytic efficiency. Journal of Nanosciences and Nanotech-nology, 19(1), 383-388.
[33] Tian, Y., & Tatsuma, T. (2005). Mechanisms and applications of plasmon-induced charge separation at TiO2 films loaded with gold nanoparticles. Journal of American Chemical Society, 127(20), 7632-7637.

[34] Zhang, X., Wang, H., & Xu, B.-Q. (2005). Remarkable nanosize effect of zirconia in Au/ZrO2 catalyst for CO oxidation. The Journal of Physical Chemistry B, 109(19), 9678-9683.

[35] Chen, L., Ma, D., & Bao, X. (2007). Hydrogen treatment-induced surface reconstruction:  Formation of superoxide species on activated carbon over Ag/activated carbon catalysts for selective oxidation of CO in H2-rich gases. The Journal of Physical Chemistry C, 111(5), 2229-2234.

[36] Li, F.Wang, W., Cao, J., Liu, J., Zhan, K., You, S., Wang, Z., & Zhao, B. (2023). Fabrication of Cu-GO layered composites with enhanced thermal conductivity by ultrasonic spraying and electrodeposition. Journal of Materials Research and Technology, 24, 2442-2457.

[37] Nas, M. S., Calimli, M. H., BurhanH., Yılmaz, M., Mustafov, S. D., & Sen, F. (2019). Synthesis, charact-erization, kinetics and adsorption properties of Pt-Co@GO nano-adsorbent for methylene blue removal in the aquatic mediums using ultrasonic process systems. Journal of Molecular Liquids, 296, 112100.

[38] Liu, L., He, A., & Yao, X. (2022). Hydrothermal synthesis of GO/Pd/ZnO nanocomposite as photocatalyst for enhanced photocatalytic degradation of Azo dye under ultraviolet light irradiation. International of Journal Electrochemical Science, 17(6), 220647.

[39] Omidvar, A.,  Jaleh, B., &  Nasrollahzadeh, M. (2017). Preparation of the GO/Pd nanocomposite and its application for the degradation of organic dyes in water. Journal of Colloid and Interface Science, 496, 44-50.

[40] SunW., Hong, Y.Li, T., Chu, H.Liu, J.Feng, L., & Baghayeri, M. (2023). Biogenic synthesis of reduced graphene oxide decorated with silver nanoparticles (rGO/Ag NPs) using table olive (olea europaea) for efficient and rapid catalytic reduction of organic pollutants. Chemosphere, 310, 136759.

[41] Majeed-Khan, M. A., Sharma, B., Ahamed, M., Rana, A. H. S., & Kumar, S. (2023). Ag nano-particles decorated on rGO sheets: Green synthesis and effective photocatalytic action. Physica B: Condensed Matter, 657, 414789.

[42] Kheibarian, Z., Soleimani, E., & Mardani, H. R. (2022). Green synthesis of Cu@Ag core–shell nanoparticles as efficient colorimetric sensing for Hg(II) ion. Applied Physics A,128(6), 466 (10 Pages).
[43] Hojjati, M., & Soleimani, E. (2021). Highly dispersible Fe3O4-Ag@OPO(OH)2 nanocomposites as a novel eco-friendly magnetic retrievable catalyst for the reduction of p-nitrophenol. Journal of the Chinese Chemical Socitey, 68(2), 322-332.
[44] Amir-FaizM. S., Che-Azurahanim, C. A., Yazid, Y., SurianI, A. B. Siti-Nurul-AiN, M J. (2020). Preparation and characterization of graphene oxide from tea waste and it's photocatalytic application of TiO2/graphene nanocomposite, Materials Research Express, 7(1), 015613.
[45] Balu-Mahendran, G., Jothi-Ramalingam, S., Balaguru-Rayappan, J. B., Kesavan, S., Periathambi, T., & Nesakumar, N. (2020). Green preparation of reduced graphene oxide by Bougainvillea glabra flower extract and sensing application. Journal of Materials Science: Materials in Electronics, 31, 14345–14356.
[46] Adyani, S. H., & Soleimani, E. (2019). Green synthesis of Ag/Fe3O4/RGO nanocomposites by Punica Granatum peel extract: Catalytic activity for reduction of organic pollutants, International of Journal of Hydrogen Energy, 44(5), 2711-2730.
[47] Kheibarian, Z., Soleimani, E., & Mardani, H. R. (2023). Photocatalytic activity of Cu@Ag BNCs synthesized by the green method: Photodegradation methyl orange and indigo carmine. Inorganic and Nano-Metal Chemistry, 53(4), 355-365.
[48] Veisi, H., Kavian, M., Hekmati, M., & Hemmati, S. (2019). Biosynthesis of the silver nanoparticles on the graphene oxide’s surface using Pistacia atlantica leaves extract and its antibacterial activity against some human pathogens. Polyhedron, 161, 338-345.
[49] Parvathi, E., Akshaya, C. V., Dilraj, N., Arjun, G., & Deepak, N. K. (2023). Green synthesis of reduced graphene oxide by shallots. Materials Today Proceedings, 2023, https://doi.org/10.1016/j.matpr.2023.04.309.
[50] Das, R. S., Lingait, D., Gaharwar, S. S., Kumar, A., & Gokhale, S. (2023). Green synthesis of reduced graphene oxide with multiple environmental applications. Journal of Photochemistry and Photobiology A: Chemistry, 444, 115021.
[51] Raj, S., Mali, S. C., & Trivedi, R. (2018). Green synthesis and characterization of silver nanoparticles using Enicostemma axillare (Lam.) leaf extract. Biochemical and Biophysical Research Communications, 503(4), 2814-2819.
[52] Muthu, M. S., Xavier, S. S. J., Ajith, P., & Anand, D. P. (2022). Preparation and characterization studies of nano graphene oxide. Materials Today Proceedings, 66 (Part 4), 2449–2454.
[53] Freire, J. M. A., Moreira, ´I. O., França, A. M. M., da Silva, L. T. V., dos Santos, L. P. M., Medeiros, S. L. S., de Vasconcelos, I. F., Loiola, A. R., Antunes, R. A., do Nascimento, R. F., & Longhinotti, E. (2023). Functionalized magnetic graphene oxide composites for selective toxic metal adsorption. Environmental Nanotechnology, Monitoring & Management, 20, 100843.
[54] Arya, A., Mishra, V., & Chundawat, T.S. (2019). Green synthesis of silver nanoparticles from green algae (Botryococcus braunii) and its catalytic behavior for the synthesis of benzimidazoles. Chemical Data Collections, 20, 100190.
[55] Bulin, C. (2023). Adsorption mechanism and removal efficiency of magnetic graphene oxide-chitosan hybrid on aqueous Zn(II). International Journal of Biological Macromolecules, 241, 124588.
[56] Shilpa, M. P., Shetty, S. J., Bhat, S. S., Surabhi, S., Murari, M. S., Bhat, V. S., Inamdar, S. R., Ravikirana, Jeong, J.-R., Morales, D. V., & Gurumurthy, S. C.  (2023). Nanogold-decorated reduced graphene oxide for catalytic hydrogenation of 4-nitrophenol. Materials Chemistry and Physics, 307, 128145.
[57] Chettri, P., Vendamani, V. S., Tripathi, A., Singh, M. K., Pathak, A. P., & Tiwari, A. (2017). Green synthesis of silver nanoparticle-reduced graphene oxide using Psidium guajava and its application in SERS for the detection of methylene blue. Applied Surface Science, 406, 312-318.
[58] Nasrollahzadeh, M., Sajadi, S. M., & Khalaj, M. (2014). Green synthesis of copper nanoparticles using aqueous extract of the leaves of Euphorbia esula L and their catalytic activity for ligand-free Ullmann-coupling reaction and reduction of 4-nitrophenol. RSC Advances4(88), 47313-47318.
[59] Weiwei, W., Wenfang, W., Xiaoli, C., Yucheng, W. & Lingshu D. (2015). Synthesis and characterization of Ag/graphene nano-composite. Rare Metal Materials and Engineering, 44(9), 2138-2142.
[60] Chettri, P., Vendamani, V. S., Tripathi, A., Singh, M. K., Pathak, A. P., & Tiwari, A. (2017). Green synthesis of silver nanoparticle-reduced graphene oxide using Psidium guajava and its application in SERS for the detection of methylene blue. Applied Surface Science, 406, 312-318.
[61] Mohd-Shah N. R. A.Yunus R. M.Rosman N. N.Wong W. Y.Arifin K.& Minggu L.J. (2021) Current progress on 3D graphene-based photocatalysts: From synthesis to photocatalytic hydrogen production. International Journal of Hydrogen Energy, 46(14), 9324-9340.

[62] VermaP., Yuan, K.Kuwahara, Y., MoriK., & Yamashita, H. (2018). Enhancement of plasmonic activity by Pt/Ag bimetallic nanocatalyst supported on mesoporous silica in the hydrogen production from hydrogen storage material. Applied Catalysis B: Environmental, 223, 10-15.

[63] RömerI., WhiteT. A., BaaloushaM., ChipmanK., ViantM. R., & Lead, J. R. (2011). Aggregation and dispersion of silver nanoparticles in exposure media for aquatic toxicity tests, Journal of Chromatography A, 1218 (27),  2011, 4226-4233.

[64] HareeshK., JoshiR. P., DahiwaleS. S., BhoraskarV. N., & Dhole, S. D. (2016). Synthesis of Ag-reduced graphene oxide nanocomposite by gamma radiation assisted method and its photocatalytic activity, Vacuum, 124, 40-45.

[65] Dutta, K., Datta, A., & Majumder, S. (2022). Design of plasmonic solar photocatalyst: Judicially coupled hot carrier induced surface plasmon of Ag with graphene, Optical Materials, 123, 111887.
[66] Shirzad-Siboni, M., Khataee, A., & Joo, S. W. (2014). Kinetics and equilibrium studies of removal of an azo dye from aqueous solution by adsorption onto scallop. Journal of Industrial and Engineering Chemistry, 20(2), 610-615.
[67] Garg, V. K., Amita, M., Kumar, R., & Gupta, R. (2004). Basic dye (methylene blue) removal from simulated wastewater by adsorption using Indian Rosewood sawdust: A timber industry waste. Dyes and Pigments, 63(3), 243-250.
[68] Chakrabarti, S., & Dutta, B. K. (2004). Photocatalytic degradation of model textile dyes in wastewater using ZnO as semiconductor catalyst. Journal of Hazardous Materials, 112(3), 269-278.
[69] Ashfaq M., Talreja N., Chauhan D., Rodríguez C. A., Mera A. C., & Viswanathan M.R. (2022). Synthesis of reduced graphene oxide incorporated bimetallic (Cu/Bi) nanorods based photocatalyst materials for the degradation of gallic acid and bacteria. Journal of Industrial and Engineering Chemistry, 110, 447-455.