شیمى کاربردى روز

شیمى کاربردى روز

کاربرد میکرو استخراج فاز جامد پخشی برپایه نانو ذرات مغناطیسی نیکل فریت برای پیش‌تغلیظ و اندازه‌گیری هگزافلومورون توسط طیف سنجی تحرک یونی در نمونه های محیطی و غذایی

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
دانشکده شیمی، دانشگاه دامغان، دامغان، ایران
چکیده
یک روش میکرو استخراج فاز جامد پخشی با طیف‌سنجی تحرک یونی (IMS) به عنوان روشی ساده و سریع برای تعیین حشره‌کش هگزافلومورن مورد استفاده قرار گرفت. در این روش، از نانو‌ذرات مغناطیسی نیکل فریت به عنوان جاذب و از دی کلرواتان به عنوان حلال شوینده استفاده گردید. در این روش پس از پایان مراحل استخراج و سانتریفیوژ، حلال شوینده حاوی آنالیت جهت آنالیز به دستگاه IMS تزریق گردید. تاثیر پارامترهای مختلف از جمله pH، نوع و حجم بافر، نوع و حجم حلال شوینده، مقدار جاذب و زمان استخراج بر روی این فرایند بررسی شده است. تحت شرایط بهینه، منحنی کالیبراسیون در محدوده ng.mL-11-150) 9998/0= (R2 خطی می‌باشد و حد تشخیص روش ng mL-13/0 بدست آمد. مقدار انحراف استاندارد نسبی (10n=) برای غلظت-هایng.mL-1 10 و100 به ترتیب 4/3% و 4/1% بدست آمد. این روش به عنوان روشی مناسب برای اندازه‌گیری هگزافلومورن درنمونه‌های آب، خاک، گوجه‌فرنگی، آب میوه و پسته مورد استفاده قرار گرفت.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Application of nickle ferrite based dispersive solid phase microextraction for preconcentration and determination of hexaflumuron by ion mobility spectrometry in environmental and food samples

نویسندگان English

Seyedeh Tahereh Rostami
Behzad Aibaghi
School of Chemistry, Damghan University, Damghan, Iran
چکیده English

A solid phase microextraction method coupled with ion mobility spectrometry (IMS) was employed as a simple and rapid approach for the determination of the hexaflumuron insecticide. In this method, nickel ferrite magnetic nanoparticles were used as adsorbent and dichloromethane was used as desorption solvent. In this method, after the end of the extraction steps and centrifugation, the desorption solvent containing the analyte was injected into the IMS instrument for analysis. The effects of various parameters including pH, type and volume of buffer, type and volume of desorption solvent, amount of adsorbent, and extraction time on this process were investigated. Under optimized conditions, the calibration curve is linear in the range of 1-150 ng mL-1 (R2=0.9998), and detection limit of the method was obtained 0.3 ng mL-1. The relative standard deviation (RSD) values (n=10) for concentrations of 10 and 100 ng mL-1 were found to be 1.4% and 3.4%, respectively. This method was applied as a suitable approach for the measurement of hexaflumuron in water, soil, tomato, fruit juice, and pistachio samples.

کلیدواژه‌ها English

Sample preparation
Pesticide
Trace analysis
Magnetic nanomaterials
Plasma chromatography
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