شیمى کاربردى روز

شیمى کاربردى روز

مطالعه رفتار الکتروشیمیایی و ابرخازنی کمپلکس کاتوسن خودانباشته بر روی الکترود میکرو فیبر کربنی

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
دانشکده شیمی کاربردی، دانشگاه صنعتی مالک اشتر، شاهین شهر، اصفهان، ایران
چکیده
در این تحقیق رفتار ابرخازنی فیلم لایه نازک ماده ردوکسی و مایع کاتوسن بر روی الکترود میکرو فیبر کربنی (Cat/CMF) در الکترولیت آبی سولفات سدیم مطالعه شده است. سطح الکترود اصلاح شده برای تشخیص کیفیت تشکیل فیلم ماده ردوکسی و محتوی عنصر آهن آن با میکروسکوپ الکترونی روبشی (SEM)، طیف سنجی فروشکست القایی لیزری (LIBS)، طیف بینی مادون قرمز بازتاب کلی تضعیف شده (ATR-IR) و تبدیل فوریه ارزیابی شد و کارایی الکترودها و ظرفیت ویژه آنها تکنیک‌های با ولتامتری سیکلی (CV)، طیف سنجی امپدانس الکتروشیمیایی (EIS) و شارژ-دشارژ گالوانواستاتیک (GCD) در سیستم سه الکترودی ارزیابی و مقایسه شدند. آزمون‌های الکتروشیمیایی نشان داد که فرایندهای الکترودی تحت کنترل فرایند نفوذ با ضریب انتقال کاتدی نزدیک به 48/0 است و مقاومت انتقال بار الکترود اصلاح شده نیز در مطالعات EIS تا 23 برابر بهبود می‌یابد. به صورت نوعی، ظرفیت ویژه الکترود Cat/CMF در دانسیته جریان A/g 55/0 برابر F/g 76/39 است. در دانسیته جریان A/g 83/0 رفتار ابرخازنی لایه نازک خودانباشته کاتوسن دارای دانسیته انرژی Wh/kg 5/2 در دانسیته توان W/kg 8/373 می‌باشد. همچنین ظرفیت ویژه خازنی در شارژ-دشارژهای متوالی تا 3000 سیکل، تقریبا 30% کاهش می‌یابد.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Electrochemical Characteristics and Supercapacitance of the Self-Assembled Catocene Complex on Carbon Microfiber Electrode

نویسندگان English

Sajjad Damiri
Zahra Samiei
Hamid reza Pouretedal
Department of Applied Chemistry, Maleke-ashtar University of Technology, Shahin-shahr, Esfahan, I. R. Iran
چکیده English

To prevent a potential energy crisis in the near future, it is necessary to develop high-performance energy storage devices, such as supercapacitors (SCs). In this study, we fabricated a thin film of a new redox catalyst, catocene, on a carbon microfiber electrode (Cat/CMF) using a self-assembled method. We then investigated its electrochemical behaviour in an aqueous sodium sulfate electrolyte. Different techniques were used to evaluate the surface quality of the thin film and its iron content, including scanning electron microscopy (SEM), laser-induced breakdown spectroscopy (LIBS), and attenuated total reflection infrared spectroscopy (ATR). The efficiency and specific capacity of the electrodes were then assessed using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge (GCD) methods in a three-electrode system. Electrochemical tests revealed that the redox processes are diffusion-controlled, exhibiting battery-like behaviour. The cathodic transfer coefficient is close to 0.48, and the charge transfer resistance of the modified electrode is improved up to 23 times compared to the bare electrode. At a current density of 0.55 A/g, the specific capacity of the Cat/CMF electrode is 39.76 F/g. At a current density of 0.83 A/g, the catocene thin film exhibits a supercapacitance behaviour with an energy density of 2.5 Wh/kg and a power density of 373.8 W/kg.

کلیدواژه‌ها English

Supercapacitor
Catocene
Carbon microfiber
electrochemical
Specific capacitance
[1] Wang, Y., Zhang, L., Hou, H., Xu, W., Duan, G., He, S., Liu, K., & Jiang, S. (2020). Recent progress in carbon-based materials for supercapacitor electrodes: a review. Journal of Materials Science, 56(1), 173–200.
[2] Sharma, S., & Chand, P. (2023). Supercapacitor and electrochemical techniques: A brief review. Results in Chemistry, 5, 100885.
[3] Shah, S. S., Aziz, M. A., Mahfoz, W., & Akhtaruzzaman, M. (2023). Types of Supercapacitors. In Biomass-Based Supercapacitors: Design, Fabrication and Sustainability (pp. 93–104). John Wiley & Sons, Ltd.
[4] Shaikh, N. S., Ubale, S. B., Mane, V. J., Shaikh, J. S., Lokhande, V. C., Praserthdam, S., Lokhande, C. D., & Kanjanaboos, P. (2022). Novel electrodes for supercapacitor: Conducting polymers, metal oxides, chalcogenides, carbides, nitrides, MXenes, and their composites with graphene. Journal of Alloys and Compounds, 893, 161998.
[5] Han, Y., & Dai, L. (2019). Conducting Polymers for Flexible Supercapacitors. Macromolecular Chemistry and Physics, 220(3), 1800355.
[6] Ma, Y., Xie, X., Yang, W., Yu, Z., Sun, X., Zhang, Y., Yang, X., Kimura, H., Hou, C., Guo, Z., & Du, W. (2021). Recent advances in transition metal oxides with different dimensions as electrodes for high-performance supercapacitors. Advanced Composites and Hybrid Materials, 4(4), 906–924.
[7] Liang, R., Du, Y., Xiao, P., Cheng, J., Yuan, S., Chen, Y., Yuan, J., & Chen, J. (2021). Transition Metal Oxide Electrode Materials for Supercapacitors: A Review of Recent Developments. Nanomaterials 11(5), 1248.
[8] Yan, J., Liu, T., Liu, X., Yan, Y., & Huang, Y. (2022). Metal-organic framework-based materials for flexible supercapacitor application. Coordination Chemistry Reviews, 452, 214300.
[9] Ansari-asl, Z., Neisi, Z., Sedaghat, T., & Nobakht, V. (2019). Synthesis, characterization, and electrochemical properties of polyaniline/Co(II) metal-organic framework composites. Applied Chemistry Today, 14(51), 251–266.
[10] Lakra, R., Kumar, R., Sahoo, P. K., Thatoi, D., & Soam, A. (2021). A mini-review: Graphene based composites for supercapacitor application. Inorganic Chemistry Communications, 133, 108929.
[11] Wu, Q. S., Bigdeli, F., Rouhani, F., Gao, X. M., Kaviani, H., Li, H. J., Wang, W., Liu, K. G., Hu, M. L., Cai, X. Q., & Morsali, A. (2021). New 3D Porous Silver Nanopolycluster as a Highly Effective Supercapacitor Electrode: Synthesis and Study of the Optical and Electrochemical Properties. Inorganic Chemistry, 60(3), 1523–1532.
[12] Damiri, S., Varzaneh, H. Y., & Ebrahimi, H. R. (2011). PEG-assisted electrochemical growth of lead oxide nanodendrites with strongly enhanced charge storage capacity. Materials Letters, 65(17–18), 2598–2600.
[13] Yu, M., & Feng, X. (2019). Thin-Film Electrode-Based Supercapacitors. Joule, 3(2), 338–360.
[14] Oje, A. I., Ogwu, A. A., Mirzaeian, M., Oje, A. M., & Tsendzughul, N. (2019). Silver thin film electrodes for supercapacitor application. Applied Surface Science, 488, 142–150.
[15] You, M., Zhang, W., Yan, X., Jiang, H., Miao, J., Li, Y., Zhou, W., Zhu, Y., & Cheng, X. (2021). V2O5 nanosheets assembled on 3D carbon fiber felt as a free-standing electrode for flexible asymmetric supercapacitor with remarkable energy density. Ceramics International, 47(3), 3337–3345.
[16] Prabu, V., Geetha, K., Sekar, R., & Ulaganathan, M. (2023). Binder-Free Electro-Deposited MnO2 @3D Carbon Felt Network: A Positive Electrode for 2V Aqueous Supercapacitor. Energy Technology, 11(2), 2201345.
[17] Azizi, S., Askari, M. B., Rozati, S. M., & Masoumnezhad, M. (2024). Nickel ferrite coated on carbon felt for asymmetric supercapacitor. Chemical Physics Impact, 8, 100543.
[18] Achour, W., Ynineb, F., Hadjersi, T., Moulai, F., Ifires, M., Khen, A., Manseri, A., & Kechouane, M. (2023). Hydrothermal deposition of urchin-like NiCo2O4 on carbon felt as performed flexible electrodes for supercapacitors. Journal of Applied Electrochemistry, 53(7), 1405–1419.
[19] Du, L., Zhang, R., Zhou, J., Li, J., Huang, X., & Luo, J. (2022). Microwave-synthesized self-supporting CoSe2/carbon fiber felt electrode for ultra–high cycling life flexible supercapacitors. International Journal of Hydrogen Energy, 47(26), 12855–12864.
[20] Ali, G. A. M., Megiel, E., Cieciórski, P., Thalji, M. R., Romański, J., Algarni, H., & Chong, K. F. (2020). Ferrocene functionalized multi-walled carbon nanotubes as supercapacitor electrodes. Journal of Molecular Liquids, 318, 114064.
[21] Hu, M. L., Abbasi-Azad, M., Habibi, B., Rouhani, F., Moghanni-Bavil-Olyaei, H., Liu, K. G., & Morsali, A. (2020). Electrochemical Applications of Ferrocene-Based Coordination Polymers. ChemPlusChem, 85(11), 2397–2418.
[22] Teimuri-Mofrad, R., Hadi, R., & Abbasi, H. (2019). Synthesis and characterization of ferrocene-functionalized reduced graphene oxide nanocomposite as a supercapacitor electrode material. Journal of Organometallic Chemistry, 880, 355–362.
[23] Khordadpour Siahkal Mahalleh, M., Ahour, F., & Keshipour, S. (2023). Development of copper electrochemical sensor using D-penicillamine functionalized graphene oxide modified electrode. Applied Chemistry Today, 18(67), 71–90.
[24] Arvand, M., Pourhabib, A., & Mousavi, S. J. (2023). Electrochemical exfoliated graphene oxide nanosheets modified graphite electrode for clozapine sensing. Applied Chemistry Today, 18(69), 57–68.
[25] Habibi Shabestary, B., & Golbon Haghighi, M. (2023). Synthesis, Characterization and DNA binding studies of Platinum Complexes with Imine Ferrocene Ligand. Applied Chemistry Today, 18(66), 225–240.
[26] Nemati, F., Farrokhi, H., & Jazirehpour, M. (2017). Chemical synthesis and characterization of polypyrrole with novel morphology prepared via self-reactive MnO2 microcube as sacriï‌cial template and oxidizing agent. Applied Chemistry Today, 12(45), 65–70.
[27] Saha, P., Yadav, V. K., Gurunarayanan, V., Ramapanicker, R., Singh, J. K., & Gopakumar, T. G. (2020). Revealing the Limits of Intermolecular Interactions: Molecular Rings of Ferrocene Derivatives on Graphite Surface. Journal of Physical Chemistry Letters, 11(1), 297–302.
[28] Kurapati, N., Pathirathna, P., Ziegler, C. J., & Amemiya, S. (2019). Adsorption and Electron-Transfer Mechanisms of Ferrocene Carboxylates and Sulfonates at Highly Oriented Pyrolytic Graphite. ChemElectroChem, 6(22), 5651–5660.
[29] Damiri, S., Pouretedal, H. R., & Mahmoudi, M. (2022). Sensitive Electrocatalytic Assay of Cyclotetramethylene Tetranitramine (HMX) Explosive on Carbon Nanotube/Ag Nanocomposite Electrode. Iranian Journal of Catalysis, 12(1), 69–76.
[30] Sa’at, M., Yarmohammadi, M., Zamani Pedram, M., Shahidzadeh, M., & Amini-Fazl, M. S. (2019). Evaluation of the catocene/graphene oxide nanocomposite catalytic activity on ammonium perchlorate thermal decomposition. International Journal of Chemical Kinetics, 51(5), 337–345.
[31] Feng, H., Suo, Q., Zhang, C., Liu, X., & Ma, X. (2021). Component Analysis of Industrial Grade Catocene and Preparation of Binuclear Ferrocene. Acta Armamentarii, 42(5), 961.
[32] Xiaoju, L., Qi, S., Haitao, F., Chi, Z., Xiaoyan, M., Xiaoju, L., Qi, S., Haitao, F., Chi, Z., & Xiaoyan, M. (2021). Theoretical and experimental study on synthesis of high-content catocene. Journal of Beijing University of Aeronautics and Astronautics, 47(12), 2514–2520.
[33] Saxena, K., Kumar, P., & Jain, V. K. (2011). Synthesis of carbon microfibers by chemical vapor deposition during the catalytic decomposition of turpentine oil. New Carbon Materials, 26(5), 356–360.
[34] Idris, N., Lahna, K., Fadhli, & Ramli, M. (2017). Study on Emission Spectral Lines of Iron, Fe in Laser-Induced Breakdown Spectroscopy (LIBS) on Soil Samples. Journal of Physics: Conference Series, 846(1).
[35] Ralchenko, Y., & Kramida, A. (2020). Development of NIST Atomic Databases and Online Tools. Atoms, 8(3), 56.
[36] Paul, A., Muthukumar, S., & Prasad, S. (2020). Application of Room Temperature Ionic Liquid As Sensing Modality for Selective Detection of Important Phenylpyperidine Analogue. ECS Meeting Abstracts, MA2020-01(35), 2451–2451.
[37] Chemistry, N. T.-J. of S., & 2007,  undefined. (2007). Cyclic voltammetric studies of ferrocene in nonaqueous solvents in the temperature range from 248.15 to 298.15 K. SpringerNG TsierkezosJournal of Solution Chemistry, 36(3), 289–302.
[38] Xiaoju, L., Qi, S., Haitao, F., Chi, Z., Xiaoyan, M., Xiaoju, L., Qi, S., Haitao, F., Chi, Z., & Xiaoyan, M. (2021). Theoretical and experimental study on synthesis of high-content catocene. Journal of Beijing University of Aeronautics and Astronautics, 47(12), 2514–2520.
[39] Faulkner, A. J. B. L. R. (2008). Electrochemical Methods: Fundamentals and Applications, 2nd Edition. In Wiley.
[40] Noori, A., El-Kady, M. F., Rahmanifar, M. S., Kaner, R. B., & Mousavi, M. F. (2019). Towards establishing standard performance metrics for batteries, supercapacitors and beyond. Chemical Society Reviews, 48(5), 1272–1341.
[41] Gogotsi, Y., & Penner, R. M. (2018). Energy Storage in Nanomaterials - Capacitive, Pseudocapacitive, or Battery-like? ACS Nano, 12(3), 2081–2083.
[42] Damiri, S., Pouretedal, H. R., & Heidari, A. (2016). Fabrication of a nanostructured TiO2/carbon nanotube composite electrode for voltammetric and impedimetric determination of NTO explosive in the water and soil samples. International Journal of Environmental Analytical Chemistry, 96(11), 1059–1073.
[43] Feng, Y., Qu, H., Wang, Y., Wang, L., Wang, Y., Yang, D., Ding, B., Sun, Y., Guo, J., & Dai, S. (2024). Facile Synthesis of Ag-Doped Urchin-like MnO2 on Carbon Cloth for Supercapacitors. Materials, 17(6), 1312.
[44] Li, T., Jiao, X., You, T., Dai, F., Zhang, P., Yu, F., Hu, L., Ding, L., Zhang, L., Wen, Z., & Wu, Y. (2019). Hexagonal boron nitride nanosheet/carbon nanocomposite as a high-performance cathode material towards aqueous asymmetric supercapacitors. Ceramics International, 45(4), 4283–4289.