شیمى کاربردى روز

شیمى کاربردى روز

نقش افزودنی دوپامین در افزایش عملکرد باتری لیتیوم یون مبتنی بر LFP

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
1 گروه شیمی کاربردی، دانشکده شیمی، دانشگاه کاشان، کاشان
2 گروه شیمی، دانشگاه اصفهان، اصفهان، ایران
3 گروه شیمی، دانشگاه سیستان و بلوچستان، زاهدان، ایران
4 دانشکده مهندسی مکانیک، دانشگاه علم و صنعت ایران (IUST)، تهران، ایران
چکیده
افزودنی‌های باتری لیتیوم یون عملکرد، طول عمر و پایداری باتری‌های لیتیوم یون را از طریق تثبیت رابط‌های الکترود-الکترولیت، بهبود خواص الکترولیت و تسهیل استفاده کارآمد از منابع و تسهیل مهاجرت سریع لیتیوم بهبود می‌بخشند. با این وجود، ایمنی آتش سوزی، عمر مفید طولانی مدت و نگهداری ظرفیت، همه نگرانی های حیاتی برای باتری های لیتیوم یون تجاری هستند رویکردهای متعددی به منظور بهبود عملکرد الکتروشیمیایی، افزایش ایمنی و طول عمر بالاتر مورد بررسی قرار گرفته شده است. افزودنی‌ها یکی از راه‌های امیدوارکننده برای برآوردن الزامات بالا هستند. در این مقاله، ما از دوپامین به عنوان یک افزودنی ارزان و ایمن (در مقایسه با ترکیبات آلی) با غلظت 0.05 درصد وزنی به الکترولیت در باتری سل کامل لیتیوم یون با کاتد LFP آند گرافیت (باتری سیلندری 38120)، استفاده کردیم. نتایج ما افزایش پایداری حرارتی، تسریع تشکیل فاز الکترولیت جامد در گرافیت، بهبود CEI در سطح کاتد LFP و حفظ ظرفیت 100٪ پس از 200 چرخه را نشان داد. این افزودنی نقش سازنده در قبال کاتد LFP، برای افزایش عملکرد باتری لیتیوم یون بدون ایجاد خطرات احتراق یا محیطی ایجاد می‌کند.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

The Role of Dopamine Additive Toward Enhancing Performance of LFP-based Li-ion Battery

نویسندگان English

Farshad Boorboor-Ajdari 1
Fereshteh Abbasi 1
Abolfazl Fathollahi Zonouz 2
Ali Heydari 3
Hasan Shokoui Mehrabani 4
1 Department of Applied Chemistry, Faculty of Chemistry, University of Kashan, Kashan
2 Department of Chemistry, University of Isfahan, Isfahan, Iran.
3 Department of Chemistry, University of Sistan and Baluchestan, Zahedan, Iran
4 Faculty of Mechanical Engineering, Iran University of Science and Technology (IUST), Tehran, Iran
چکیده English

Li-ion battery additives improve the performance, lifetime, and stability of Li-ion batteries by stabilizing electrode-electrolyte interfaces, improving electrolyte properties, facilitating efficient use of resources, and facilitating rapid lithium migration. However, fire safety, long service life, and capacity maintenance are all critical concerns for commercial Li-ion batteries. Several approaches have been explored to improve electrochemical performance, increase safety, and higher lifetime. Additives are one promising way to meet the above requirements. In this paper, we used dopamine as a cheap and safe additive (compared to organic compounds) at a concentration of 0.05 wt% to the electrolyte in a lithium-ion full-cell battery with a graphite anode LFP cathode (cylindrical battery 38120). Our results showed increased thermal stability, accelerated solid electrolyte interphase formation in graphite, improved CEI on the LFP cathode surface, and maintained 100% capacity after 200 cycles. This additive plays a constructive role in the LFP cathode to increase the performance of the Li-ion battery without causing combustion or environmental hazards.

کلیدواژه‌ها English

Lithium iron phosphate cathode
additive
dopamine
solid electrolyte interface
cycle life
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