شیمى کاربردى روز

شیمى کاربردى روز

نانوذرات هسته-پوسته مغناطیسی Fe3O4@SiO2 عامل‌دار شده با 1و4-دی هیدروکسی آنتراکوئینون به‌عنوان یک جاذب مؤثر و قابل بازیافت به‌منظور حذف مس دو ظرفیتی از محلول‌های آبی

نوع مقاله : مقاله علمی پژوهشی

نویسندگان
1 گروه پژوهشی شیمی و فرآیند، پژوهشگاه نیرو، تهران، ایران
2 گروه شیمی، دانشگاه پیام نور، تهران، ایران
چکیده
در این پژوهش، نانوذرات هسته-پوسته مغناطیسی Fe3O4@SiO2 عامل‌دار شده با مولکول‌های 1و4-دی هیدروکسی آنتراکوئینون سنتز شدند و به-منظور حذف یون‌های مس دو ظرفیتی از محلول‌های آبی مورد استفاده قرار گرفتند. سپس خصوصیات ساختاری، کریستالی، مورفولوژی سطحی، اندازه نانوذرات، خواص مغناطیسی و پایداری حرارتی نانوذرات سنتزی با بکارگیری آنالیزهای تعیین مشخصه طیف‌سنجی مادون قرمز تبدیل فوریه، پراش اشعه ایکس، میکروسکوپ الکترونی روبشی-نشر میدانی، میکروسکوپ الکترونی عبوری، مغناطیس‌سنج نمونه ارتعاشی و توزین گرمایی مورد بررسی و شناسایی قرار گرفتند. پس از سنتز نانوجاذب مغناطیسی، تأثیر مقادیر مختلف جاذب و مطالعه سینتیکی جذب در حذف یو‌ن‌های مس دو ظرفیتی مورد بررسی قرار گرفت که نتایج نشان داد که بکارگیری 14 میلی‌گرم جاذب منجر به حذف یون مس با ماکزیمم جذب 96% در دمای محیط در مدت زمان 28 دقیقه و در 7 = pHمی‌شود. در نهایت قابلیت بازیافت و استفاده مجدد Fe3O4@SiO2-DAQ در فرآیند جذب-واجذب یون Cu2+ با بکارگیری یک مگنت مغناطیسی مورد بررسی قرار گرفت که نتایج مؤید آن است که این نانوکامپوزیت سنتزی یک جاذب مؤثر با عملکرد عالی به منظور حذف یون مس دو ظرفیتی از محلول‌های آبی می‌باشد.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Fe3O4@SiO2 Magnetic Core-Shell Nanoparticles Functionalized with 1,4-dihydroxyanthraquinone as an Effective and Recyclable Adsorbent for Removal of Copper Ion from Aqueous Solutions

نویسندگان English

Majid Ghahraman Afshar 1
Mahsa Rajabi 2
Mahmood Payehghadr 2
Niloufar Bahrami Panah 2
1 Chemistry and Process Research Department, Niroo Research Institute (NRI), Tehran, Iran
2 Department of Chemistry, Payame Noor University, Tehran, Iran
چکیده English

In this research, Fe3O4@SiO2 magnetic core-shell nanoparticles functionalized with 1,4-dihydroxyanthraquinone molecules were synthesized and used to remove divalent copper ions from aqueous solutions. Then, the structural, crystalline, surface morphology, nanoparticle size, magnetic properties and thermal stability of synthetic nanoparticles were determined using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscope, field emission scanning electron microscope, transmission electron microscope, vibrating sample magnetometer and thermal gravimetric analysis were investigated and identified. After the synthesis of magnetic nano adsorbent, the effect of different amount of adsorbent and study of absorption kinetics in the removal of divalent copper ions was investigated and the results showed that the use of 14 mg of adsorbent leads to the removal of copper ions with a maximum absorption of 96% at ambient temperature in a period of 28 minutes and at pH = 7. Finally, the recyclability and reusability of Fe3O4@SiO2-DAQ in the copper ion adsorption-desorption process was investigated using a magnetic magnet and the results confirm that this synthetic nanocomposite is an effective adsorbent with excellent performance to remove divalent copper ions.

کلیدواژه‌ها English

Fe3O4@SiO2 Nanocomposite
1
4-Dihydroxyanthraquinone
Properties of Nanoabsorbents
Bivalent Copper
Efficient Removal
Magnetic Separation
[1] Das, P.N., Jithesh, K., and Raj, K.G. (2021). Recent developments in the adsorptive removal of heavy metal ions using metal-organic frameworks and graphene-based adsorbents. Journal of the Indian Chemical Society, 98(11), 100188.
[2] Esmaeilpour, M., Larimi, A., Asgharinezhad, A., Ghahramanafshar, M., and Faghihi, M. (2022). Silica nanoparticles extracted from rice husk and functionalized with dendrimer as an effective recyclable adsorbent to remove divalent cadmium from aqueous solutions. Journal of Applied Research of Chemical-Polymer Engineering, 6(1), 63-76.
[3] Guo, X., Feng, Q., Fan, D., Wang, Z., Ren, Y., Sun, B., and Yang, D. (2022). An agent-based dynamic reliability modeling method for multistate systems considering fault propagation: A case study on subsea Christmas trees. Process Safety and Environmental Protection, 158, 20-33.
[4] Soleimani, M., Ghaderi, S., Afshar, M.G., and Soleimani, S. (2012). Synthesis of molecularly imprinted polymer as a sorbent for solid phase extraction of bovine albumin from whey, milk, urine and serum. Microchemical Journal, 100, 1-7.
[5] Afshar, M.G., Tercier-Waeber, M., Wehrli, B., and Bakker, E. (2017). Direct sensing of total alkalinity profile in a stratified lake. Geochem. Perspect. Lett, 3(1), 85-93.
[6] Hojamberdiev, M., Daminova, S.S., Kadirova, Z.C., Sharipov, K.T., Mtalo, F., and Hasegawa, M. (2018). Ligand-immobilized spent alumina catalyst for effective removal of heavy metal ions from model contaminated water. Journal of Environmental Chemical Engineering, 6(4), 4623-4633.
[7] Safir, I., Ngo, K.X., Abraham, J.N., Afshar, M.G., Pavlova, E., and Nardin, C. (2015). Synthesis and structure formation in dilute aqueous solution of a chitosan-DNA hybrid. Polymer, 79, 29-36.
[8] Zeng, T., Yu, Y., Li, Z., Zuo, J., Kuai, Z., Jin, Y., Wang, Y., Wu, A., and Peng, C. (2019). 3D MnO2 nanotubes@ reduced graphene oxide hydrogel as reusable adsorbent for the removal of heavy metal ions. Materials Chemistry and Physics, 231, 105-108.
[9] Asgharinezhad, A.A., Esmaeilpour, M., and Afshar, M.G. (2024). Synthesis of magnetic Fe3O4@ SiO2 nanoparticles decorated with polyvinyl alcohol for Cu (II) and Cd (II) ions removal from aqueous solution. Chemical Papers, 1-16.
[10] Esmaeilpour, M. and Ghahraman Afshar, M. (2023). Magnetic Nanoadsorbent: Preparation, characterization, and Adsorption Properties for Removal of Copper (II) from Aqueous Solutions. Applied Chemistry Today, 18(69), 11-20.
[11] Niknam, E., Naffakh-Moosavy, H., Moosavifard, S.E., and Afshar, M.G. (2022). Amorphous V-doped Co3S4 yolk-shell hollow spheres derived from metal-organic framework for high-performance asymmetric supercapacitors. Journal of Alloys and Compounds, 895, 162720.
[12] Afshar, M.G., Crespo, G.A., and Bakker, E. (2015). Thin‐Layer Chemical Modulations by a Combined Selective Proton Pump and pH Probe for Direct Alkalinity Detection. Angewandte Chemie, 127(28), 8228-8231.
[13] Barkade, S., Sable, S., Ashtekar, V., and Pandit, V. (2022). Removal of lead and copper from wastewater using Bael fruit shell as an adsorbent. Materials Today: Proceedings, 53, 65-70.
[14] Gupta, V. and Nayak, A. (2012). Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles. Chemical engineering journal, 180, 81-90.
[15] Soleimani, M., Ghahraman Afshar, M., and Sedghi, A. (2013). Amino-functionalization of multiwall carbon nanotubes and its use for solid phase extraction of mercury ions from fish sample. International Scholarly Research Notices, 2013.
[16] Wang, L., Hu, D., Kong, X., Liu, J., Li, X., Zhou, K., Zhao, H., and Zhou, C. (2018). Anionic polypeptide poly (γ-glutamic acid)-functionalized magnetic Fe3O4-GO-(o-MWCNTs) hybrid nanocomposite for high-efficiency removal of Cd (II), Cu (II) and Ni (II) heavy metal ions. Chemical engineering journal, 346, 38-49.
[17] Esmaeilpour, M., Ghahraman Afshar, M., and Ghaseminejad, H. (2024). Investigation of water consumption in Shahid Montazer Ghaem steam Power Plant and technical-economic evaluation of the boilers' blowdown recycling solutions. Nashrieh Shimi va Mohandesi Shimi Iran, 42(4), 177-189.
[18] Soleimani, M., Mahmodi, M.S., Morsali, A., Khani, A., and Afshar, M.G. (2011). Using a new ligand for solid phase extraction of mercury. Journal of hazardous materials, 189(1-2), 371-376.
[19] Emenike, E.C., Adeniyi, A.G., Omuku, P.E., Okwu, K.C., and Iwuozor, K.O. (2022). Recent advances in nano-adsorbents for the sequestration of copper from water. Journal of Water Process Engineering, 47, 102715.
[20] Esmaeilpour, M., Ghahraman Afshar, M., and Kazemnejadi, M. (2023). Preparation, characterization, and adsorption properties of bis-salophen schiff base ligand immobilized on Fe3O4@ SiO2 nanoparticles for removal of lead (II) from aqueous solutions. Applied Chemistry, 18(66), 125-146.
[21] Khalil, N.A., Rahman, A.S.A., Huraira, A.M.A., Janurin, S.N.D.F., Fizal, A.N.S., Ahmad, N., Zulkifli, M., Hossain, M.S., and Yahaya, A.N.A. (2023). Magnetic chitosan hydrogel beads as adsorbent for copper removal from aqueous solution. Materials Today: Proceedings, 74, 499-503.
[22] Ghahraman Afshar, M., Esmaeilpour, M., and Ghaseminejad, H. (2024). Microbial corrosion affected by environmental factors in cooling tower of Bandar Abbas power plant. Journal of Environmental Studies, 49(4), 389-400.
[23] Niknam, E., Naffakh-Moosavy, H., and Afshar, M.G. (2022). Electrochemical performance of Nickel foam electrode in Potassium Hydroxide and Sodium Sulfate electrolytes for supercapacitor applications. Journal of Composites and Compounds, 4(12), 149-152.
[24] Zandbaaf, S., Khorrami, M.R.K., and Afshar, M.G. (2022). Genetic algorithm based artificial neural network and partial least squares regression methods to predict of breakdown voltage for transformer oils samples in power industry using ATR-FTIR spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 273, 120999.
[25] Soleimani, M., Afshar, M.G., and Ganjali, M.R. (2013). High selective methadone sensor based on molecularly imprinted polymer carbon paste electrode modified with carbon nanotubes. Sensor Letters, 11(10), 1983-1991.
[26] Esmaeilpour, M., Ghahraman Afshar, M., Noroozi Tisseh, Z., and Ghahremanzadeh, R. (2023). Removal of copper and chromium ions from aqueous solutions with magnetic nanoparticles functionalized with N-phosphonomethyl amino diacetic acid. Journal of Applied Research of Chemical-Polymer Engineering, 7(1), 33-46.
[27] Javidi, J., Esmaeilpour, M., and Khansari, M.R. (2015). Synthesis, characterization and application of core–shell magnetic molecularly imprinted polymers for selective recognition of clozapine from human serum. Rsc Advances, 5(89), 73268-73278.
[28] Miller, M., Prinz, G., Cheng, S.-F., and Bounnak, S. (2002). Detection of a micron-sized magnetic sphere using a ring-shaped anisotropic magnetoresistance-based sensor: A model for a magnetoresistance-based biosensor. Applied Physics Letters, 81(12), 2211-2213.
[29] Hanifehpour, Y., Mirtamizdoust, B., and Golbedaghi, R. (2024). Synthesis, characterization and X-ray crystal structure of a new cocrystal complex of and preparation the related nano cadmium (II) oxide. Applied Chemistry Today, 19(71), 9-22.
[30] Niknam, E., Naffakh-Moosavy, H., Moosavifard, S.E., and Afshar, M.G. (2021). Multi-shelled bimetal V-doped Co3O4 hollow spheres derived from metal organic framework for high performance supercapacitors. Journal of Energy Storage, 44, 103508.
[31] Aghayee, M., Zolfigol, M.A., Keypour, H., Yarie, M., and Mohammadi, L. (2016). Synthesis and characterization of a novel magnetic nano‐palladium Schiff base complex: application in cross‐coupling reactions. Applied Organometallic Chemistry, 30(8), 612-618.
[32] Asgharinezhad, A.A.A., Esmaeilpour, M., and Afshar, M.G. (2023). Synthesis of magnetic Fe3O4@ SiO2 nanoparticles decorated with polyvinyl alcohol for heavy metal ion removal from aqueous solution.
[33] Chen, X., Zhu, J., Chen, Z., Xu, C., Wang, Y., and Yao, C. (2011). A novel bienzyme glucose biosensor based on three-layer Au–Fe3O4@ SiO2 magnetic nanocomposite. Sensors and Actuators B: Chemical, 159(1), 220-228.
[34] Esmaeilpour, M. and Ghahraman Afshar, M. (2023). Magnetic Nanoadsorbent: Preparation, characterization, and Adsorption Properties for Removal of Copper (II) from Aqueous Solutions. Applied Chemistry.
[35] Esmaeilpour, M., Javidi, J., Dehghani, F., and Dodeji, F.N. (2014). Fe 3 O 4@ SiO 2–imid–PMA n magnetic porous nanospheres as recyclable catalysts for the one-pot synthesis of 14-aryl-or alkyl-14 H-dibenzo [a, j] xanthenes and 1, 8-dioxooctahydroxanthene derivatives under various conditions. New Journal of Chemistry, 38(11), 5453-5461.
[36] Esmaeilpour, M., Larimi, A., Ghahramanafshar, M., and Faghihi, M. (2023). Ethylenediaminetetraacetic acid coated Fe₃O₄@ SiO₂ nanocomposite: An effective adsorbent for the removal of copper ions from aqueous system. Applied Chemistry, 17(65), 45-54.
[37] Hossienzadeh, M., Hassanpour, A., AliHosseini, M., Safardoust, H., and Mirzaei, M. (2024). Synthesis and Characterization of NiO/ZnO Nanocomposite and its Application in Ibuprofen Drug Delivery. Applied Chemistry Today, 19(71), 69-80.
[38] Néel, B., Ghahraman Asfhar, M., Crespo, G.A., Pawlak, M., Dorokhin, D., and Bakker, E. (2014). Nitrite‐Selective Electrode Based On Cobalt (II) tert‐Butyl‐Salophen Ionophore. Electroanalysis, 26(3), 473-480.
[39] Asgharinezhad, A.A., Esmaeilpour, M., and Afshar, M.G. (2024). Synthesis of magnetic Fe3O4@ SiO2 nanoparticles decorated with polyvinyl alcohol for Cu (II) and Cd (II) ions removal from aqueous solution. Chemical Papers, 78(6), 3799-3814.
[40] Ghahraman Afshar, M., Payehghadr, M., Bahrami Panah, N., and Akbari, M. (2024). Fe3O4@SiO2 magnetic core-shell nanoparticles functionalized with 1,4-dihydroxyanthraquinone as an effective and recyclable adsorbent for the removal of divalent nickel from aqueous solutions. Iranian Chemical Engineering Journal, -.
[41] Kaamyabi, S., Karimi Hajishoreh, N., and akbarzadeh, a. (2024). Design of termo-sensitive molecularly imprinted polymers(MIP) and in vitro evaluation of controlled release of Eptifibatide drug. Applied Chemistry Today, 19(71), 81-94.
[42] Afshar, M.G., Azimi, M., Habibi, N., Masihi, H., and Esameilpour, M. (2023). Batch and continuous bleaching regimen in the cooling tower of Montazer Ghaem power plant. Journal of Hazardous Materials Advances, 11, 100339.
[43] Niknam, E., Ghahraman Afshar, M., Ghaseminejad, H., and Esamaeilpour, M. (2022). Pharmaceutical Pollutants Removal by Using Electrochemical Oxidation Technique. Journal of Water and Wastewater; Ab va Fazilab (in persian), 33(4), 71-81.
[44] Deng, Y., Qi, D., Deng, C., Zhang, X., and Zhao, D. (2008). Superparamagnetic high-magnetization microspheres with an Fe3O4@ SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins. Journal of the American Chemical Society, 130(1), 28-29.
[45] Dindarloo Inaloo, I., Majnooni, S., Eslahi, H., and Esmaeilpour, M. (2020). Nickel (II) nanoparticles immobilized on EDTA-modified Fe3O4@ SiO2 nanospheres as efficient and recyclable catalysts for ligand-free Suzuki–Miyaura coupling of aryl carbamates and sulfamates. ACS omega, 5(13), 7406-7417.
[46] Sardarian, A.R., Kazemnejadi, M., and Esmaeilpour, M. (2019). Bis-salophen palladium complex immobilized on Fe 3 O 4@ SiO 2 nanoparticles as a highly active and durable phosphine-free catalyst for Heck and copper-free Sonogashira coupling reactions. Dalton Transactions, 48(9), 3132-3145.
[47] Bloom, H., Briggs, L., and Cleverley, B. (1959). 33. Physical properties of anthraquinone and its derivatives. Part I. Infrared spectra. Journal of the Chemical Society (Resumed), 178-185.
[48] Sharghi, H., Beyzavi, M.H., Safavi, A., Doroodmand, M.M., and Khalifeh, R. (2009). Immobilization of porphyrinatocopper nanoparticles onto activated multi‐walled carbon nanotubes and a study of its catalytic activity as an efficient heterogeneous catalyst for a click approach to the three‐component synthesis of 1, 2, 3‐triazoles in water. Advanced Synthesis & Catalysis, 351(14‐15), 2391-2410.
[49] Huang, X., Wang, G., Yang, M., Guo, W., and Gao, H. (2011). Synthesis of polyaniline-modified Fe3O4/SiO2/TiO2 composite microspheres and their photocatalytic application. Materials Letters, 65(19-20), 2887-2890.
[50] Zarnegar, Z. and Safari, J. (2014). Fe 3 O 4@ chitosan nanoparticles: a valuable heterogeneous nanocatalyst for the synthesis of 2, 4, 5-trisubstituted imidazoles. Rsc Advances, 4(40), 20932-20939.
[51] Banerjee, S.S. and Chen, D.-H. (2007). Fast removal of copper ions by gum arabic modified magnetic nano-adsorbent. Journal of hazardous materials, 147(3), 792-799.
[52] Zhang, L., Yu, C., Zhao, W., Hua, Z., Chen, H., Li, L., and Shi, J. (2007). Preparation of multi-amine-grafted mesoporous silicas and their application to heavy metal ions adsorption. Journal of Non-Crystalline Solids, 353(44-46), 4055-4061.
[53] Wang, J., Ma, X., Fang, G., Pan, M., Ye, X., and Wang, S. (2011). Preparation of iminodiacetic acid functionalized multi-walled carbon nanotubes and its application as sorbent for separation and preconcentration of heavy metal ions. Journal of hazardous materials, 186(2-3), 1985-1992.
[54] Kołodyńska, D., Kowalczyk, M., and Hubicki, Z. (2014). Evaluation of iron-based hybrid materials for heavy metal ions removal. Journal of Materials Science, 49, 2483-2495.
[55] Karami, H. (2013). Heavy metal removal from water by magnetite nanorods. Chemical engineering journal, 219, 209-216.
[56] Xu, X., Cao, X., Zhao, L., Wang, H., Yu, H., and Gao, B. (2013). Removal of Cu, Zn, and Cd from aqueous solutions by the dairy manure-derived biochar. Environmental Science and Pollution Research, 20, 358-368.
[57] Phuengprasop, T., Sittiwong, J., and Unob, F. (2011). Removal of heavy metal ions by iron oxide coated sewage sludge. Journal of hazardous materials, 186(1), 502-507.
[58] Lee, S.-M., Laldawngliana, C., and Tiwari, D. (2012). Iron oxide nano-particles-immobilized-sand material in the treatment of Cu (II), Cd (II) and Pb (II) contaminated waste waters. Chemical engineering journal, 195, 103-111.
[59] Yeung, P.-T., Chung, P.-Y., Tsang, H.-C., Tang, J.C.-O., Cheng, G.Y.-M., Gambari, R., Chui, C.-H., and Lam, K.-H. (2014). Preparation and characterization of bio-safe activated charcoal derived from coffee waste residue and its application for removal of lead and copper ions. Rsc Advances, 4(73), 38839-38847.