ساخت و بررسی عملکرد غشای کامپوزیتی لایه نازک پلی‌آمیدی در نمک‌ زدایی و حذف ناپروکسن از محلول‌های آبی

نوع مقاله : مقاله علمی پژوهشی

نویسندگان

دانشکده مهندسی شیمی، نفت و گاز، دانشگاه سمنان، سمنان 19111-35131، ایران

چکیده

هدف از این مطالعه، حذف داروی ضد التهابی غیر استروئیدی ناپروکسن از محلول‌های آبی به کمک غشای کامپوزیتی لایه نازک (TFC) بر پایه‌ی پلی‌اترسولفون (PES) می‌باشد. این غشای نانوفیلتراسیون با استفاده از روش پلیمریزاسیون بین سطحی (IP) و با تشکیل یک لایه‌ی پلی‌آمیدی فعال بر روی سطح بستر میکرومتخلخل ایجاد گردید. مورفولوژی، زبری و بار سطح غشای کامپوزیتی سنتز شده به ترتیب به کمک میکروسکوپ الکترونی روبشی نشری میدانی(FESEM) ، میکروسکوپ نیروی اتمی (AFM) و پتانسیل زتا مورد بررسی قرار گرفت. به منظور ارزیابی عملکرد غشای نانوفیلتراسیون ساخته شده، میزان پس‌زنی نمک‌های تک ظرفیتی و دو ظرفیتی NaCl، Na2SO4، MgCl2 و MgSO4 اندازه‌گیری گردید. نتایج بدست آمده نشان داد که میزان پس‌زنی نمک‌های حاوی آنیون دو ظرفیتی سولفات، Na2SO4 وMgSO4 ، در فشار عملیاتی 4 بار به ترتیب برابر با 90/5% و 61/8 % می‌باشد. دستاورد حاصل از این پژوهش می‌تواند دیدگاه وسیعی در رابطه با استفاده از غشاهای کامپوزیتی لایه نازک در حذف ناپروکسن به عنوان یک داروی آبگریز از محلول‌های آبی ایجاد نماید.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Fabrication and Performance Evaluation of the Polyamide Thin Film Composite Membrane in Desalination and Removal of Naproxen from Aqueous Solutions

نویسندگان [English]

  • Masoud Nasiri
  • Sara Abdi
Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan 35131-19111, Iran
چکیده [English]

The aim of this study is to remove the non-steroidal anti-inflammatory drug naproxen from aqueous solutions using a polyethersulfone (PES)-based thin film composite (TFC) membrane. This nanofiltration membrane was fabricated using the interfacial polymerization (IP) method and by forming an active polyamide layer on the microporous substrate surface. The morphology, roughness, and surface charge of the synthesized composite membrane were investigated using the field emission scanning electron microscope (FESEM), atomic force microscopy (AFM), and zeta potential, respectively. To evaluate the performance of the fabricated nanofiltration membrane, the rejection rate of monovalent and divalent salts of NaCl, Na2SO4, MgCl2 and MgSO4 was measured. The obtained results showed that the rejection rate of salts containing divalent sulfate anion, Na2SO4 and MgSO4, at the operating pressure of 4 bar is equal to 90.5% and 61.8%, respectively. The result of this research can create a broad perspective regarding the use of thin film composite membranes in the removal of naproxen as a hydrophobic drug from aqueous solutions.

کلیدواژه‌ها [English]

  • Nanofiltration
  • Thin film composite membrane
  • Interfacial polymerization
  • Desalination
  • Naproxen
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