سنتز نانوکامپوزیت مغناطیسی Fe3O4/SiO2/TiO2/CoIIITHPP به عنوان کاتالیزگر در واکنش کمولومینسانس سیستم H2O2-لومینول

نوع مقاله : مقاله علمی پژوهشی

نویسندگان

دانشکده شیمی، دانشگاه مازندران، بابلسر، ایران

چکیده

واکنش نورتابی شیمیایی لومینول به دلیل حساسیت بالا به حضور کاتالیزگر و سیگنال زمینه کم از روش‌های کمی شناخته شده در طیف‌‌سنجی تجزیه‌ای است. در این تحقیق نانوکامپوزیت مغناطیسی Fe3O4/SiO2/TiO2/CoIIITHPP (THPP : تترا هیدروکسی فنیل پورفیرین) تهیه و با طیف سنجی تبدیل فوریه مادون قرمز (FT-IR)، پراش پرتو ایکس (XRD)، مغناطیس ارتعاشی نمونه (VSM)، میکروسکوپ الکترونی روبشی (SEM)، میکروسکوپ الکترونی عبوری (TEM) و طیف سنجی پراکندگی انرژی پرتو ایکس (EDS) شناسایی شد. از این نانو کامپوزیت مغناطیسی برای اولین بار به عنوان کاتالیزگر واکنش کمولومینسانس استفاده شد و فعالیت کاتالیزی بسیار خوبی را در واکنش کمولومینسانس سیستم H2O2- لومینول نشان داد. بازیابی این کاتالیزگر به آسانی با به کارگیری میدان مغناطیسی خارجی انجام‌پدیر است.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

The synthesis of Fe3O4/SiO2/TiO2/CoIIITHPP magnetic nanocomposite as catalyst in reaction of luminol-H2O2 chemiluminescence system

نویسندگان [English]

  • ensieh gholamrezapor
  • Abbas Eslami
  • Afsaneh Nemati
  • Mohamad Javad Chaichi
Department of Inorganic Chemistry, University of Mazandaran, Babolsar, Mazandaran, Iran
چکیده [English]

The luminol chemiluminescent reaction is among well-known quantitative methods in analytical spectroscopy due to its high sensitivity to presence of catalyst and low background signal. In this study, magnetic nanocomposite of Fe3O4/SiO2/TiO2/CoIIITHPP (THPP : tetrahyroxyphenylporphyrin) has been synthesized by co-precipitation method and characterized with fourior transform-infrared (FT-IR), X-ray photoelectron spectroscopy (XRD), vibrating sample magnetometer (VSM), scanning electron microscope (SEM), trasmiddion electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS. For the fist time, this magnetic nanocomposite has been used as catalyst of chemolumincence reactions and showed high catalytic effect on the luminol-H2O2 system. The recovery of catalyst was easily performed by applying the external magnetic field.

کلیدواژه‌ها [English]

  • magnetic nanocomposite
  • Chemiluminescence
  • luminol
  • porphyrin
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