ساخت بیوکامپوزیت شیشه زیست فعال 58S/ کیتوسان/ زئولیت 13X با استفاده از روش فاز مایع

نوع مقاله : مقاله علمی پژوهشی

نویسندگان

پژوهشکده فناوری های شیمیایی، سازمان پژوهش های علمی و صنعتی ایران، تهران، ایران

چکیده

در این مقاله بیوکامپوزیتی با استفاده از شیشه زیست فعال 58S، کیتوسان با جرم مولکولی بالا و زئولیت 13X به روش فاز مایع تهیه شد. مشخصه‌یابی‌ فیزیکی نمونه با استفاده از آنالیزهای FT-IR، XRD، FE-SEM و EDX انجام گرفت. نتایج حاصل از FT-IR وجود باندهای مربوط به هر یک از اجزاء را نشان می‌دهد. همچنین مقایسه طیف FT-IR و الگوی XRD مربوط به کیتوسان با کامپوزیت تهیه شده، کراسلینک شدن کیتوسان را تایید می‌نماید. مقاومت فشاری نمونه تهیه شده با استفاده از نمودار تنش-کرنش مشخص گردید. براساس این آزمایش مقاومت فشاری نمونه برابر MPa 43/51 می‌باشد. همچنین زیست فعالی بیوکامپوزیت ساخته شده در محیط مایع شبیه‌سازی شده بدن (SBF)، در دمای 37 درجه سانتی‌گراد و به مدت 3 روز بررسی شد که زیست فعالی مطلوبی را از خود نشان داد. الگوی XRD و تصاویر FE-SEM بیوکامپوزیت قبل و بعد از غوطه‌وری در محلول SBF، نشان دهنده رشد آپاتیت بر روی بیوکامپوزیت است. همچنین طیف EDX حضور تمام اجزاء بیوکامپوزیت را تایید می‌کند. براساس مطالعات پیشین، کامپوزیت تهیه شده در این مقاله نسبت به کامپوزیت‌های مشابه ویژگی‌های مطلوب‌تری را از خود نشان داده است.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Fabrication of bioactive glass 58S/chitosan/zeolite 13X biocomposite using liquid phase method

نویسندگان [English]

  • nakisa moghaddam
  • Nasrin Oroujzadeh
  • Alireza Salehirad
Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), P.O.Box 33535-111, Tehran, Iran
چکیده [English]

In this paper, a biocomposite was prepared by liquid phase method using 58S bioactive glass, high molecular weight chitosan and 13X zeolite. Physical characterization of the sample was performed using FT-IR, XRD, FE-SEM and EDX analysis. Results of FT-IR showed the presence of bands related to each component. Also, a comparison between FT-IR spectrum and XRD pattern of chitosan with the ones of prepared composite confirms the cross-linking of chitosan. The compressive strength of the sample was determined using the stress-strain diagram. According to this test, the compressive strength of the sample is 51.43 MPa. Also, the bioactivity of the biocomposite was studied in the simulated body fluid (SBF) at 37 ° C for 3 days, which showed a favorable bioactivity. The XRD pattern and FE-SEM images of the biocomposite before and after immersion in SBF solution show the growth of apatite on the biocomposite. The EDX spectrum also confirms the presence of all components. According to the previous studies, the composite prepared in this paper has more desirable properties than similar composites.

کلیدواژه‌ها [English]

  • Biocomposite
  • Bioactive glass
  • Chitosan
  • Zeolite
  • Liquid phase method

This is an open access article under the CC-BY-SA 4.0 license.( https://creativecommons.org/licenses/by-sa/4.0/)

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